Abstract
A novel electron deficient β-octakis(methylthio)porphycene, along with its Zn(ii) and Ni(ii) derivatives, was synthesized for the first time. The macrocyclic structure exhibits core ruffling with a largely red shifted absorption band (∼750 nm) and also a large enhancement in the third order nonlinear optical response.
Original language | English |
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Pages (from-to) | 7705-7708 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 51 |
Issue number | 36 |
DOIs | |
Publication status | Published - 2015 May 4 |
Bibliographical note
Publisher Copyright:© The Royal Society of Chemistry 2015.
All Science Journal Classification (ASJC) codes
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry