π-Extended tetrathiafulvalene BODIPY (ex-TTF-BODIPY): A redox switched "on-off-on" electrochromic system with two near-infrared fluorescent outputs

Nathan L. Bill, Jong Min Lim, Christina M. Davis, Steffen Bähring, Jan O. Jeppesen, Dongho Kim, Jonathan L. Sessler

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

A π-extended tetrathiafulvalene-boradiazaindacene chimera, ex-TTF-BODIPY, has been prepared. The resulting system undergoes sequential one-electron oxidations, allowing access to both the mono-oxidized radical cationic and dicationic states. Additionally, ex-TTF-BODIPY displays electrochromic and electrofluorochromic behaviour in the near-IR portion of the electromagnetic spectrum and functions as a redox switched "on-off-on" emissive system. This journal is

Original languageEnglish
Pages (from-to)6758-6761
Number of pages4
JournalChemical Communications
Volume50
Issue number51
DOIs
Publication statusPublished - 2014 Jun 28

Fingerprint

On-off control systems
Display devices
Infrared radiation
Oxidation
Electrons
Oxidation-Reduction
tetrathiafulvalene
4,4-difluoro-4-bora-3a,4a-diaza-s-indacene

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Bill, Nathan L. ; Lim, Jong Min ; Davis, Christina M. ; Bähring, Steffen ; Jeppesen, Jan O. ; Kim, Dongho ; Sessler, Jonathan L. / π-Extended tetrathiafulvalene BODIPY (ex-TTF-BODIPY) : A redox switched "on-off-on" electrochromic system with two near-infrared fluorescent outputs. In: Chemical Communications. 2014 ; Vol. 50, No. 51. pp. 6758-6761.
@article{5390f5d2ed974f02b279a44b0aba8447,
title = "π-Extended tetrathiafulvalene BODIPY (ex-TTF-BODIPY): A redox switched {"}on-off-on{"} electrochromic system with two near-infrared fluorescent outputs",
abstract = "A π-extended tetrathiafulvalene-boradiazaindacene chimera, ex-TTF-BODIPY, has been prepared. The resulting system undergoes sequential one-electron oxidations, allowing access to both the mono-oxidized radical cationic and dicationic states. Additionally, ex-TTF-BODIPY displays electrochromic and electrofluorochromic behaviour in the near-IR portion of the electromagnetic spectrum and functions as a redox switched {"}on-off-on{"} emissive system. This journal is",
author = "Bill, {Nathan L.} and Lim, {Jong Min} and Davis, {Christina M.} and Steffen B{\"a}hring and Jeppesen, {Jan O.} and Dongho Kim and Sessler, {Jonathan L.}",
year = "2014",
month = "6",
day = "28",
doi = "10.1039/c4cc02567a",
language = "English",
volume = "50",
pages = "6758--6761",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "51",

}

π-Extended tetrathiafulvalene BODIPY (ex-TTF-BODIPY) : A redox switched "on-off-on" electrochromic system with two near-infrared fluorescent outputs. / Bill, Nathan L.; Lim, Jong Min; Davis, Christina M.; Bähring, Steffen; Jeppesen, Jan O.; Kim, Dongho; Sessler, Jonathan L.

In: Chemical Communications, Vol. 50, No. 51, 28.06.2014, p. 6758-6761.

Research output: Contribution to journalArticle

TY - JOUR

T1 - π-Extended tetrathiafulvalene BODIPY (ex-TTF-BODIPY)

T2 - A redox switched "on-off-on" electrochromic system with two near-infrared fluorescent outputs

AU - Bill, Nathan L.

AU - Lim, Jong Min

AU - Davis, Christina M.

AU - Bähring, Steffen

AU - Jeppesen, Jan O.

AU - Kim, Dongho

AU - Sessler, Jonathan L.

PY - 2014/6/28

Y1 - 2014/6/28

N2 - A π-extended tetrathiafulvalene-boradiazaindacene chimera, ex-TTF-BODIPY, has been prepared. The resulting system undergoes sequential one-electron oxidations, allowing access to both the mono-oxidized radical cationic and dicationic states. Additionally, ex-TTF-BODIPY displays electrochromic and electrofluorochromic behaviour in the near-IR portion of the electromagnetic spectrum and functions as a redox switched "on-off-on" emissive system. This journal is

AB - A π-extended tetrathiafulvalene-boradiazaindacene chimera, ex-TTF-BODIPY, has been prepared. The resulting system undergoes sequential one-electron oxidations, allowing access to both the mono-oxidized radical cationic and dicationic states. Additionally, ex-TTF-BODIPY displays electrochromic and electrofluorochromic behaviour in the near-IR portion of the electromagnetic spectrum and functions as a redox switched "on-off-on" emissive system. This journal is

UR - http://www.scopus.com/inward/record.url?scp=84901755282&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84901755282&partnerID=8YFLogxK

U2 - 10.1039/c4cc02567a

DO - 10.1039/c4cc02567a

M3 - Article

C2 - 24831301

AN - SCOPUS:84901755282

VL - 50

SP - 6758

EP - 6761

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 51

ER -