11% Organic Photovoltaic Devices Based on PTB7-Th: PC71BM Photoactive Layers and Irradiation-Assisted ZnO Electron Transport Layers

Havid Aqoma, Sujung Park, Hye Yun Park, Wisnu Tantyo Hadmojo, Seung Hwan Oh, Sungho Nho, Do Hui Kim, Jeonghoon Seo, Sungmin Park, Du Yeol Ryu, Shinuk Cho, Sung Yeon Jang

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15 Citations (Scopus)

Abstract

The enhancement of interfacial charge collection efficiency using buffer layers is a cost-effective way to improve the performance of organic photovoltaic devices (OPVs) because they are often universally applicable regardless of the active materials. However, the availability of high-performance buffer materials, which are solution-processable at low temperature, are limited and they often require burdensome additional surface modifications. Herein, high-performance ZnO based electron transporting layers (ETLs) for OPVs are developed with a novel g-ray-assisted solution process. Through careful formulation of the ZnO precursor and g-ray irradiation, the pre-formation of ZnO nanoparticles occurs in the precursor solutions, which enables the preparation of high quality ZnO films. The g-ray assisted ZnO (ZnO-G) films possess a remarkably low defect density compared to the conventionally prepared ZnO films. The low-defect ZnO-G films can improve charge extraction efficiency of ETL without any additional treatment. The power conversion efficiency (PCE) of the device using the ZnO-G ETLs is 11.09% with an open-circuit voltage (VOC), short-circuit current density (JSC), and fill factor (FF) of 0.80 V, 19.54 mA cm-2, and 0.71, respectively, which is one of the best values among widely studied poly[4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b;4,5-b′]dithiophene-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene-)-2-carboxylate-2-6-diyl)]: [6,6]-phenyl-C71-butyric acid methyl ester (PTB7-Th:PC71BM)-based devices.

Original languageEnglish
Article number1700858
JournalAdvanced Science
Volume5
Issue number7
DOIs
Publication statusPublished - 2018 Jul

All Science Journal Classification (ASJC) codes

  • Medicine (miscellaneous)
  • Chemical Engineering(all)
  • Biochemistry, Genetics and Molecular Biology (miscellaneous)
  • Materials Science(all)
  • Engineering(all)
  • Physics and Astronomy(all)

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    Aqoma, H., Park, S., Park, H. Y., Hadmojo, W. T., Oh, S. H., Nho, S., Kim, D. H., Seo, J., Park, S., Ryu, D. Y., Cho, S., & Jang, S. Y. (2018). 11% Organic Photovoltaic Devices Based on PTB7-Th: PC71BM Photoactive Layers and Irradiation-Assisted ZnO Electron Transport Layers. Advanced Science, 5(7), [1700858]. https://doi.org/10.1002/advs.201700858