2,5-Thienylene-bridged triangular and linear porphyrin trimers

Jianxin Song, So Young Jang, Shigeru Yamaguchi, Jeyaraman Sankar, Satoru Hiroto, Naoki Aratani, Jae Yoon Shin, Shanmugam Easwaramoorthi, Kil Suk Kim, Dongho Kim, Hiroshi Shinokubo, Atsuhiro Osuka

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Abstract

(Figure Presented) A question of shape: Palladium-catalyzed cross-coupling of borylporphyrins has led to the synthesis of a β-to-β thienylene-bridged porphyrin dimer and two types of trimer (see picture; gray C; white H, pink Ni, yellow S, blue N). The ladderlike trimer exhibits a very large two-photon absorption cross-section (17300 GM) at 800 nm, while that of the triangular trimer is moderate in comparison (8600 GM).

Original languageEnglish
Pages (from-to)6004-6007
Number of pages4
JournalAngewandte Chemie - International Edition
Volume47
Issue number32
DOIs
Publication statusPublished - 2008 Jul 28

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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    Song, J., Jang, S. Y., Yamaguchi, S., Sankar, J., Hiroto, S., Aratani, N., Shin, J. Y., Easwaramoorthi, S., Kim, K. S., Kim, D., Shinokubo, H., & Osuka, A. (2008). 2,5-Thienylene-bridged triangular and linear porphyrin trimers. Angewandte Chemie - International Edition, 47(32), 6004-6007. https://doi.org/10.1002/anie.200802026