A belted monofacial ionophore featuring high selectivity for lithium ion complexation

Leo A. Paquette, Jinsung Tae, Eugene R. Hickey, Robin D. Rogers

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

Despite its preferred equatorial conformation in the solid state and in solution, the cis,cis-trispiro ether 1 binds readily and strongly to lithium ions. The 2:1 sandwich complex 2 is initially formed and transformed progressively into the 1:1 species 3 upon the addition of more LiClO4.

Original languageEnglish
Pages (from-to)1409-1411
Number of pages3
JournalAngewandte Chemie - International Edition
Volume38
Issue number10
DOIs
Publication statusPublished - 1999 May 17

Fingerprint

Ionophores
Complexation
Lithium
Ether
Conformations
Ethers
Ions
lithium perchlorate

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Paquette, Leo A. ; Tae, Jinsung ; Hickey, Eugene R. ; Rogers, Robin D. / A belted monofacial ionophore featuring high selectivity for lithium ion complexation. In: Angewandte Chemie - International Edition. 1999 ; Vol. 38, No. 10. pp. 1409-1411.
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A belted monofacial ionophore featuring high selectivity for lithium ion complexation. / Paquette, Leo A.; Tae, Jinsung; Hickey, Eugene R.; Rogers, Robin D.

In: Angewandte Chemie - International Edition, Vol. 38, No. 10, 17.05.1999, p. 1409-1411.

Research output: Contribution to journalArticle

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AU - Rogers, Robin D.

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