A catalytic hydroesterification process using HCO2Na, Ru3(CO)12 and alcohols for the preparation of ester modified polybutadienes

Woo Jin Park; Chang Hee Lee; Dong Su Kim; Chul Ho Jun

doi:10.1039/c5cc05815e

A catalytic hydroesterification process using HCO₂Na, Ru₃(CO)₁₂ and alcohols for the preparation of ester modified polybutadienes

Woo Jin Park, Chang Hee Lee, Dong Su Kim, Chul Ho Jun

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

A method for the transition metal catalyzed modification of polybutadiene was developed. Specifically, reactions of polybutadiene with alcohols and sodium formate in the presence of Ru₃(CO)₁₂ and 2-pyridinemethanol produce ester derivatives of polybutadiene. By using this approach, selected ratios of mixed ester derivatives of polybutadiene can be produced by employing the corresponding ratio of alcohols.

Original language	English
Pages (from-to)	14667-14670
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	78
DOIs	https://doi.org/10.1039/c5cc05815e
Publication status	Published - 2015 Aug 10

Bibliographical note

Publisher Copyright:
© The Royal Society of Chemistry 2015.

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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AU - Lee, Chang Hee

AU - Kim, Dong Su

AU - Jun, Chul Ho

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