Abstract
A method for the transition metal catalyzed modification of polybutadiene was developed. Specifically, reactions of polybutadiene with alcohols and sodium formate in the presence of Ru3(CO)12 and 2-pyridinemethanol produce ester derivatives of polybutadiene. By using this approach, selected ratios of mixed ester derivatives of polybutadiene can be produced by employing the corresponding ratio of alcohols.
| Original language | English |
|---|---|
| Pages (from-to) | 14667-14670 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 51 |
| Issue number | 78 |
| DOIs | |
| Publication status | Published - 2015 Aug 10 |
All Science Journal Classification (ASJC) codes
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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Park, W. J., Lee, C. H., Kim, D. S., & Jun, C. H. (2015). A catalytic hydroesterification process using HCO2Na, Ru3(CO)12 and alcohols for the preparation of ester modified polybutadienes. Chemical Communications, 51(78), 14667-14670. https://doi.org/10.1039/c5cc05815e