A Chemical Route to Activation of Open Metal Sites in the Copper-Based Metal-Organic Framework Materials HKUST-1 and Cu-MOF-2

Hong Ki Kim, Won Seok Yun, Min Bum Kim, Jeung Yoon Kim, Youn Sang Bae, Jae Dong Lee, Nak Cheon Jeong

Research output: Contribution to journalArticle

87 Citations (Scopus)

Abstract

Open coordination sites (OCSs) in metal-organic frameworks (MOFs) often function as key factors in the potential applications of MOFs, such as gas separation, gas sorption, and catalysis. For these applications, the activation process to remove the solvent molecules coordinated at the OCSs is an essential step that must be performed prior to use of the MOFs. To date, the thermal method performed by applying heat and vacuum has been the only method for such activation. In this report, we demonstrate that methylene chloride (MC) itself can perform the activation role: this process can serve as an alternative "chemical route" for the activation that does not require applying heat. To the best of our knowledge, no previous study has demonstrated this function of MC, although MC has been popularly used in the pretreatment step prior to the thermal activation process. On the basis of a Raman study, we propose a plausible mechanism for the chemical activation, in which the function of MC is possibly due to its coordination with the Cu2+ center and subsequent spontaneous decoordination. Using HKUST-1 film, we further demonstrate that this chemical activation route is highly suitable for activating large-area MOF films. (Chemical Equation Presented).

Original languageEnglish
Pages (from-to)10009-10015
Number of pages7
JournalJournal of the American Chemical Society
Volume137
Issue number31
DOIs
Publication statusPublished - 2015 Aug 12

Fingerprint

Methylene Chloride
Copper
Hot Temperature
Metals
Chemical activation
Dichloromethane
Gases
Vacuum
Catalysis
bis(1,3,5-benzenetricarboxylate)tricopper(II)
Sorption
Molecules

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Kim, Hong Ki ; Yun, Won Seok ; Kim, Min Bum ; Kim, Jeung Yoon ; Bae, Youn Sang ; Lee, Jae Dong ; Jeong, Nak Cheon. / A Chemical Route to Activation of Open Metal Sites in the Copper-Based Metal-Organic Framework Materials HKUST-1 and Cu-MOF-2. In: Journal of the American Chemical Society. 2015 ; Vol. 137, No. 31. pp. 10009-10015.
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A Chemical Route to Activation of Open Metal Sites in the Copper-Based Metal-Organic Framework Materials HKUST-1 and Cu-MOF-2. / Kim, Hong Ki; Yun, Won Seok; Kim, Min Bum; Kim, Jeung Yoon; Bae, Youn Sang; Lee, Jae Dong; Jeong, Nak Cheon.

In: Journal of the American Chemical Society, Vol. 137, No. 31, 12.08.2015, p. 10009-10015.

Research output: Contribution to journalArticle

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