A conditioning-free magnesium chloride complex electrolyte for rechargeable magnesium batteries

Jung Hoon Ha, Brian Adams, Jae Hyun Cho, Victor Duffort, Jong Hak Kim, Kyung Yoon Chung, Byung Won Cho, Linda F. Nazar, Si Hyoung Oh

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

The dissolution of Mg metal in AlCl3/THF using CrCl3 as a "promoter" yields a magnesium aluminum chloride complex electrolyte which shares many common features with MACC, but does not require an onerous conditioning process. This crucial advantage originates from the very high Mg to Al ratio in the new electrolyte, "MaCC", which promotes 100% coulombic efficiency for Mg in the first cycle.

Original languageEnglish
Pages (from-to)7160-7164
Number of pages5
JournalJournal of Materials Chemistry A
Volume4
Issue number19
DOIs
Publication statusPublished - 2016 Jan 1

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Magnesium Chloride
Magnesium
Electrolytes
Aluminum chloride
Dissolution
Metals
aluminum chloride

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

Ha, Jung Hoon ; Adams, Brian ; Cho, Jae Hyun ; Duffort, Victor ; Kim, Jong Hak ; Chung, Kyung Yoon ; Cho, Byung Won ; Nazar, Linda F. ; Oh, Si Hyoung. / A conditioning-free magnesium chloride complex electrolyte for rechargeable magnesium batteries. In: Journal of Materials Chemistry A. 2016 ; Vol. 4, No. 19. pp. 7160-7164.
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Ha, JH, Adams, B, Cho, JH, Duffort, V, Kim, JH, Chung, KY, Cho, BW, Nazar, LF & Oh, SH 2016, 'A conditioning-free magnesium chloride complex electrolyte for rechargeable magnesium batteries', Journal of Materials Chemistry A, vol. 4, no. 19, pp. 7160-7164. https://doi.org/10.1039/c6ta01684g

A conditioning-free magnesium chloride complex electrolyte for rechargeable magnesium batteries. / Ha, Jung Hoon; Adams, Brian; Cho, Jae Hyun; Duffort, Victor; Kim, Jong Hak; Chung, Kyung Yoon; Cho, Byung Won; Nazar, Linda F.; Oh, Si Hyoung.

In: Journal of Materials Chemistry A, Vol. 4, No. 19, 01.01.2016, p. 7160-7164.

Research output: Contribution to journalArticle

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