A Convenient Method for Olefination of vic-Diols by Lithium Iodide via Cyclic Sulfates

Doo Ok Jang; Yung Hyup Joo

doi:10.1055/s-1997-782

A Convenient Method for Olefination of vic-Diols by Lithium Iodide via Cyclic Sulfates

Doo Ok Jang, Yung Hyup Joo

Chemistry and Medical Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Reaction of cyclic sulfates of vic-diols with lithium iodide in acetone produced the corresponding olefins in excellent isolated yields at low temperature. Cyclic sulfates of trans-diols gave trans-alkenes exclusively. Cyclic sulfates of cis-diols gave a mixture of cis- and trans-alkenes. The reaction offers mild conditions and easy work-up procedures.

Original language	English
Pages (from-to)	279-280
Number of pages	2
Journal	Synlett
Volume	1997
Issue number	3
DOIs	https://doi.org/10.1055/s-1997-782
Publication status	Published - 1997

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1055/s-1997-782

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title = "A Convenient Method for Olefination of vic-Diols by Lithium Iodide via Cyclic Sulfates",

abstract = "Reaction of cyclic sulfates of vic-diols with lithium iodide in acetone produced the corresponding olefins in excellent isolated yields at low temperature. Cyclic sulfates of trans-diols gave trans-alkenes exclusively. Cyclic sulfates of cis-diols gave a mixture of cis- and trans-alkenes. The reaction offers mild conditions and easy work-up procedures.",

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AU - Joo, Yung Hyup

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N2 - Reaction of cyclic sulfates of vic-diols with lithium iodide in acetone produced the corresponding olefins in excellent isolated yields at low temperature. Cyclic sulfates of trans-diols gave trans-alkenes exclusively. Cyclic sulfates of cis-diols gave a mixture of cis- and trans-alkenes. The reaction offers mild conditions and easy work-up procedures.

AB - Reaction of cyclic sulfates of vic-diols with lithium iodide in acetone produced the corresponding olefins in excellent isolated yields at low temperature. Cyclic sulfates of trans-diols gave trans-alkenes exclusively. Cyclic sulfates of cis-diols gave a mixture of cis- and trans-alkenes. The reaction offers mild conditions and easy work-up procedures.

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M3 - Article

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ER -

A Convenient Method for Olefination of vic-Diols by Lithium Iodide via Cyclic Sulfates

Abstract

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