A Convenient Method for Olefination of vic-Diols by Lithium Iodide via Cyclic Sulfates

Doook Jang, Yung Hyup Joo

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Reaction of cyclic sulfates of vic-diols with lithium iodide in acetone produced the corresponding olefins in excellent isolated yields at low temperature. Cyclic sulfates of trans-diols gave trans-alkenes exclusively. Cyclic sulfates of cis-diols gave a mixture of cis- and trans-alkenes. The reaction offers mild conditions and easy work-up procedures.

Original languageEnglish
Pages (from-to)279-280
Number of pages2
JournalSynlett
Volume1997
Issue number3
DOIs
Publication statusPublished - 1997 Jan 1

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Alkenes
Iodides
Lithium
Sulfates
Acetone
Temperature

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

Cite this

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abstract = "Reaction of cyclic sulfates of vic-diols with lithium iodide in acetone produced the corresponding olefins in excellent isolated yields at low temperature. Cyclic sulfates of trans-diols gave trans-alkenes exclusively. Cyclic sulfates of cis-diols gave a mixture of cis- and trans-alkenes. The reaction offers mild conditions and easy work-up procedures.",
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A Convenient Method for Olefination of vic-Diols by Lithium Iodide via Cyclic Sulfates. / Jang, Doook; Joo, Yung Hyup.

In: Synlett, Vol. 1997, No. 3, 01.01.1997, p. 279-280.

Research output: Contribution to journalArticle

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AU - Joo, Yung Hyup

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N2 - Reaction of cyclic sulfates of vic-diols with lithium iodide in acetone produced the corresponding olefins in excellent isolated yields at low temperature. Cyclic sulfates of trans-diols gave trans-alkenes exclusively. Cyclic sulfates of cis-diols gave a mixture of cis- and trans-alkenes. The reaction offers mild conditions and easy work-up procedures.

AB - Reaction of cyclic sulfates of vic-diols with lithium iodide in acetone produced the corresponding olefins in excellent isolated yields at low temperature. Cyclic sulfates of trans-diols gave trans-alkenes exclusively. Cyclic sulfates of cis-diols gave a mixture of cis- and trans-alkenes. The reaction offers mild conditions and easy work-up procedures.

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