A Description of Vibrational Modes in Hexaphyrins: Understanding the Aromaticity Reversal in the Lowest Triplet State

Young Mo Sung, Juwon Oh, Koji Naoda, Taegon Lee, Woojae Kim, Manho Lim, Atsuhiro Osuka, Dongho Kim

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Aromaticity reversal in the lowest triplet state, or Baird's rule, has been postulated for the past few decades. Despite numerous theoretical works on aromaticity reversal, experimental study is still at a rudimentary stage. Herein, we investigate the aromaticity reversal in the lowest excited triplet state using a comparable set of [26]- and [28]hexaphyrins by femtosecond time-resolved infrared (IR) spectroscopy. Compared to the relatively simple IR spectra of [26]bis(rhodium) hexaphyrin (R26H), those of [28]bis(rhodium) hexaphyrin (R28H) show complex IR spectra the region for the stretching modes of conjugated rings. Whereas time-resolved IR spectra of R26H in the excited triplet state are dominated by excited state IR absorption peaks, while those of R28H largely show ground state IR bleaching peaks, reflecting the aromaticity reversal in the lowest triplet state. These contrasting IR spectral features serve as new experimental aromaticity indices for Baird's rule.

Original languageEnglish
Pages (from-to)11930-11934
Number of pages5
JournalAngewandte Chemie - International Edition
Volume55
Issue number39
DOIs
Publication statusPublished - 2016 Sep 19

Bibliographical note

Funding Information:
This work at Yonsei University was supported by Samsung Science and Technology Foundation under Project Number SSTF-BA1402-10. The quantum calculations were performed using the supercomputing resources of the Korea Institute of Science and Technology Information (KISTI). The work at Kyoto University was financially supported by the Global Research Laboratory (GRL, 2013K1A1A2A0205183) Program funded by the Ministry of Education, Science and Technology of Korea (MEST). The work at Pusan National University was supported by the National Research Foundation of Korea (NRF) grant funded by the MEST (NRF-2014R1A2A2A01002456).

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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