Structured metals can sustain a very large scattering cross-section that is induced by localized surface plasmons, which often has an adverse effect on their use as transparent electrodes in displays, touch screens, and smart windows due to an issue of low clarity. Here, we report a broadband optical cloaking strategy for the network of mesoscopic metal wires with submicrometer to micrometer diameters, which is exploited for manufacturing and application of high-clarity metal-wires-based transparent electrodes. We prepare electrospun Ag wires with 300-1800 nm in diameter and perform a facile surface oxidation process to form Ag/Ag2O core/shell heterogeneous structures. The absorptive Ag2O shell, together with the coating of a dielectric cover, leads to the cancellation of electric multipole moments in Ag wires, thereby drastically suppressing plasmon-mediated scattering over the full visible spectrum and rendering Ag wires to be invisible. Simultaneously with the effect of invisibility, the transmittance of Ag/Ag2O wires is significantly improved compared to bare Ag wires, despite the formation of an absorptive Ag2O shell. As an application example, we demonstrate that these invisible Ag wires serve as a high-clarity, high-transmittance, and high-speed defroster for automotive windshields.
Bibliographical noteFunding Information:
J.-U.P. was supported by the Ministry of Science & ICT and the Ministry of Trade, Industry and Energy (MOTIE) of Korea through the National Research Foundation (2016R1A2B3013592 and 2016R1A5A1009926), the Nano Material Technology Development Program (2015M3A7B4050308 and 2016M3A7B4910635), the Convergence Technology Development Program for Bionic Arm (NRF-2017M3C1B2085316), the Industrial Technology Innovation Program (10080577), and the Pioneer Research Center Program (NRF-2014M3C1A3001208). S.-K.K. was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF-2017R1A2B4005480) funded by the Ministry of Science, ICT, and Future Planning.
© 2018 American Chemical Society.
All Science Journal Classification (ASJC) codes
- Materials Science(all)
- Condensed Matter Physics
- Mechanical Engineering