A head-to-head comparison of α- and β-alkoxy effects on stereoselectivity. Nucleophilic additions to a cyclohexanone substituted with five axial C-O bonds

Leo A. Paquette, Jinsung Tae

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The stereochemical course of the hydride reduction and of the 1,2- addition of allylmagnesium bromide as well as the Normant reagent to 1 has been determined.

Original languageEnglish
Pages (from-to)5971-5974
Number of pages4
JournalTetrahedron Letters
Volume40
Issue number33
DOIs
Publication statusPublished - 1999 Aug 13

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Stereoselectivity
Bromides
Hydrides
alkoxyl radical
cyclohexanone

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

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title = "A head-to-head comparison of α- and β-alkoxy effects on stereoselectivity. Nucleophilic additions to a cyclohexanone substituted with five axial C-O bonds",
abstract = "The stereochemical course of the hydride reduction and of the 1,2- addition of allylmagnesium bromide as well as the Normant reagent to 1 has been determined.",
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JF - Tetrahedron Letters

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