A layer-by-layer assembly route to [Mn 1/3Co 1/3Ni 1/3]O 2 hollow spheres with electrochemical activity

Yu Ri Lee, Myong A. Woo, Kyung Min Lee, Tae Woo Kim, Jin Ho Choy, Seong Ju Hwang

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The monolayered nanosheets of layered [Mn 1/3Co 1/3Ni 1/3]O 2 are prepared by the exfoliation of protonated Li[Mn 1/3Co 1/3Ni 1/3]O 2 compound and applied as a precursor for synthesizing the hollow spheres of manganese cobalt nickel oxide. The hollow spheres of layered [Mn 1/3Co 1/3Ni 1/3]O 2 are synthesized via the layer-by-layer (LBL) coating of the nanosheets and polycations on the polystyrene (PS) beads and the following heat-treatment. According to powder X-ray diffraction and diffuse reflectance UV-vis spectroscopy, the layered crystal structure and optical property of [Mn 1/3Co 1/3Ni 1/3]O 2 nanosheets are well-maintained upon the coating on the PS beads. The high-resolution transmission electron microscopy clearly demonstrates the hollow sphere morphology of the obtained material. The electrode functionality of the [Mn 1/3Co 1/3Ni 1/3]O 2 hollow spheres is verified by cyclic voltammetry.

Original languageEnglish
Pages (from-to)1492-1495
Number of pages4
JournalJournal of Physics and Chemistry of Solids
Volume73
Issue number12
DOIs
Publication statusPublished - 2012 Dec 1

Fingerprint

Nanosheets
hollow
assembly
routes
Polystyrenes
beads
polystyrene
coatings
Coatings
Nickel oxide
cobalt oxides
nickel oxides
Manganese
High resolution transmission electron microscopy
Cobalt
Ultraviolet spectroscopy
X ray powder diffraction
Cyclic voltammetry
manganese
heat treatment

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Lee, Yu Ri ; Woo, Myong A. ; Lee, Kyung Min ; Kim, Tae Woo ; Choy, Jin Ho ; Hwang, Seong Ju. / A layer-by-layer assembly route to [Mn 1/3Co 1/3Ni 1/3]O 2 hollow spheres with electrochemical activity. In: Journal of Physics and Chemistry of Solids. 2012 ; Vol. 73, No. 12. pp. 1492-1495.
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A layer-by-layer assembly route to [Mn 1/3Co 1/3Ni 1/3]O 2 hollow spheres with electrochemical activity. / Lee, Yu Ri; Woo, Myong A.; Lee, Kyung Min; Kim, Tae Woo; Choy, Jin Ho; Hwang, Seong Ju.

In: Journal of Physics and Chemistry of Solids, Vol. 73, No. 12, 01.12.2012, p. 1492-1495.

Research output: Contribution to journalArticle

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N2 - The monolayered nanosheets of layered [Mn 1/3Co 1/3Ni 1/3]O 2 are prepared by the exfoliation of protonated Li[Mn 1/3Co 1/3Ni 1/3]O 2 compound and applied as a precursor for synthesizing the hollow spheres of manganese cobalt nickel oxide. The hollow spheres of layered [Mn 1/3Co 1/3Ni 1/3]O 2 are synthesized via the layer-by-layer (LBL) coating of the nanosheets and polycations on the polystyrene (PS) beads and the following heat-treatment. According to powder X-ray diffraction and diffuse reflectance UV-vis spectroscopy, the layered crystal structure and optical property of [Mn 1/3Co 1/3Ni 1/3]O 2 nanosheets are well-maintained upon the coating on the PS beads. The high-resolution transmission electron microscopy clearly demonstrates the hollow sphere morphology of the obtained material. The electrode functionality of the [Mn 1/3Co 1/3Ni 1/3]O 2 hollow spheres is verified by cyclic voltammetry.

AB - The monolayered nanosheets of layered [Mn 1/3Co 1/3Ni 1/3]O 2 are prepared by the exfoliation of protonated Li[Mn 1/3Co 1/3Ni 1/3]O 2 compound and applied as a precursor for synthesizing the hollow spheres of manganese cobalt nickel oxide. The hollow spheres of layered [Mn 1/3Co 1/3Ni 1/3]O 2 are synthesized via the layer-by-layer (LBL) coating of the nanosheets and polycations on the polystyrene (PS) beads and the following heat-treatment. According to powder X-ray diffraction and diffuse reflectance UV-vis spectroscopy, the layered crystal structure and optical property of [Mn 1/3Co 1/3Ni 1/3]O 2 nanosheets are well-maintained upon the coating on the PS beads. The high-resolution transmission electron microscopy clearly demonstrates the hollow sphere morphology of the obtained material. The electrode functionality of the [Mn 1/3Co 1/3Ni 1/3]O 2 hollow spheres is verified by cyclic voltammetry.

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