Abstract
A new oxathiane, derived from 5-hydroxy-1-tetralone has been synthesized in eight steps, fully characterized as cis-fused rings by 1D and 2D NMR and resolved by preparative chiral chomatography (CHIRALCEL OD-R). The second eluting (+, MeOH)-isomer was assigned (S,S)-configuration by VCD-ab initio simulation.
| Original language | English |
|---|---|
| Pages (from-to) | 2605-2611 |
| Number of pages | 7 |
| Journal | Tetrahedron Asymmetry |
| Volume | 12 |
| Issue number | 18 |
| DOIs | |
| Publication status | Published - 2001 Oct 15 |
All Science Journal Classification (ASJC) codes
- Catalysis
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
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Solladié-Cavallo, A., Balaz, M., Salisova, M., Suteu, C., Nafie, L. A., Cao, X., & Freedman, T. B. (2001). A new chiral oxathiane: Synthesis, resolution and absolute configuration determination by vibrational circular dichroism. Tetrahedron Asymmetry, 12(18), 2605-2611. https://doi.org/10.1016/S0957-4166(01)00441-4