TY - JOUR
T1 - A new chiral oxathiane
T2 - Synthesis, resolution and absolute configuration determination by vibrational circular dichroism
AU - Solladié-Cavallo, A.
AU - Balaz, M.
AU - Salisova, M.
AU - Suteu, C.
AU - Nafie, L. A.
AU - Cao, X.
AU - Freedman, T. B.
PY - 2001/10/15
Y1 - 2001/10/15
N2 - A new oxathiane, derived from 5-hydroxy-1-tetralone has been synthesized in eight steps, fully characterized as cis-fused rings by 1D and 2D NMR and resolved by preparative chiral chomatography (CHIRALCEL OD-R). The second eluting (+, MeOH)-isomer was assigned (S,S)-configuration by VCD-ab initio simulation.
AB - A new oxathiane, derived from 5-hydroxy-1-tetralone has been synthesized in eight steps, fully characterized as cis-fused rings by 1D and 2D NMR and resolved by preparative chiral chomatography (CHIRALCEL OD-R). The second eluting (+, MeOH)-isomer was assigned (S,S)-configuration by VCD-ab initio simulation.
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U2 - 10.1016/S0957-4166(01)00441-4
DO - 10.1016/S0957-4166(01)00441-4
M3 - Article
AN - SCOPUS:0035888845
VL - 12
SP - 2605
EP - 2611
JO - Tetrahedron Asymmetry
JF - Tetrahedron Asymmetry
SN - 0957-4166
IS - 18
ER -