A noble-metalate bowl: The polyoxo-6-vanado(V)-7-palladate(II) [Pd 7V6O24(OH)2]6-

Natalya V. Izarova, Nina Vankova, Abhishek Banerjee, Geoffrey B. Jameson, Thomas Heine, Florian Schinle, Oliver Hampe, Ulrich Kortz

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42 Citations (Scopus)

Abstract

Nobly born: The bowl-shaped noble metalate [PdII 7VV 6O24(OH)2] 6-(Pd7V6) comprises seven square-planar Pd IIO4 units as well as four tetrahedral VVO 4 and two square-pyramidal VVO5 addenda units (see picture). The solution stability of Pd7V6 has been demonstrated by 51V NMR spectroscopy, ESI mass spectrometry, and DFT calculations.

Original languageEnglish
Pages (from-to)7807-7811
Number of pages5
JournalAngewandte Chemie - International Edition
Volume49
Issue number42
DOIs
Publication statusPublished - 2010 Oct 11

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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    Izarova, N. V., Vankova, N., Banerjee, A., Jameson, G. B., Heine, T., Schinle, F., Hampe, O., & Kortz, U. (2010). A noble-metalate bowl: The polyoxo-6-vanado(V)-7-palladate(II) [Pd 7V6O24(OH)2]6-. Angewandte Chemie - International Edition, 49(42), 7807-7811. https://doi.org/10.1002/anie.201001738