A non-fused mono-meso-free pentaphyrin and its rhodium(i) complex

Tomoki Yoneda, Hirotaka Mori, Byung Sun Lee, Min Chul Yoon, Dongho Kim, Atsuhiro Osuka

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11 Citations (Scopus)

Abstract

5,10,15,20-Tetrakis(pentafluorophenyl) [22]pentaphyrin(1.1.1.1.1) 7 was synthesised and its bis-rhodium(i) complex 12 has been revealed to be a non-fused, yet planar pentaphyrin with an inverted pyrrole. Both 7 and 12 are aromatic, showing sharp Soret-like bands and diatropic ring currents.

Original languageEnglish
Pages (from-to)6785-6787
Number of pages3
JournalChemical Communications
Volume48
Issue number54
DOIs
Publication statusPublished - 2012 Jul 11

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All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Yoneda, T., Mori, H., Sun Lee, B., Yoon, M. C., Kim, D., & Osuka, A. (2012). A non-fused mono-meso-free pentaphyrin and its rhodium(i) complex. Chemical Communications, 48(54), 6785-6787. https://doi.org/10.1039/c2cc32054a