A novel series of heteropolynuclear metallomesogens: Organopalladium complexes with ferrocenophane-containing ligands

Oleg N. Kadkin, Jaein An, Haksoo Han, Yuri G. Galyametdinov

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

Ferrocenophane-containing (Fcph) Schiff's bases p-C12H 25O-(C6H4)CH=N(C6H4)Fcph (LAH) and p-C12H25O(C6H 4)COO-(C6H4)CH=N(C6H 4)Fcph (LBH) react with palladium(II) acetate to form μ-acetato- and chloro-bridged dimeric organo-palladium complexes. By exchanging acetato-groups with the chloride anions, μ-chloro-bridged heteropolynuclear dimers are obtained that show thermotropic smectic A phases over a temperature range of 198 to 260°C. The complexes [PdClL A]2 and [PdClLB]2 can be transformed into a variety of mixed-ligand PdII complexes by treatment with salicyl-aldimine p-C12H25O(C6H 4)COO(C6H3)(OH)CH=N(C6H 4)-Fcph (LCH) and β-aminovinyl ketone p-C 12H25O(C6H4)-COCH=CHNH(C 6H4)Fcph (LDH). The obtained mixed-ligand heterometallic complexes [PdLALC], [PdLBLC], [PdLALD] and [PdLBLD] exhibit enantiotropic, thermotropic nematic phases over a broad temperature range from 71 to 205°C. The structures of the synthesized compounds were characterized by means of 1H NMR, IR and UV spectroscopy, as well as elemental analysis. The liquid crystalline properties were studied by polarising optical microscopy and DSC.

Original languageEnglish
Pages (from-to)1682-1688
Number of pages7
JournalEuropean Journal of Inorganic Chemistry
Issue number10
DOIs
Publication statusPublished - 2008 Apr 1

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Ligands
Schiff Bases
Palladium
Ketones
Ultraviolet spectroscopy
Dimers
Nuclear magnetic resonance spectroscopy
Optical microscopy
Anions
Chlorides
Infrared spectroscopy
Crystalline materials
Temperature
Liquids
Chemical analysis
carboxyl radical
palladium(II) acetate

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

Cite this

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title = "A novel series of heteropolynuclear metallomesogens: Organopalladium complexes with ferrocenophane-containing ligands",
abstract = "Ferrocenophane-containing (Fcph) Schiff's bases p-C12H 25O-(C6H4)CH=N(C6H4)Fcph (LAH) and p-C12H25O(C6H 4)COO-(C6H4)CH=N(C6H 4)Fcph (LBH) react with palladium(II) acetate to form μ-acetato- and chloro-bridged dimeric organo-palladium complexes. By exchanging acetato-groups with the chloride anions, μ-chloro-bridged heteropolynuclear dimers are obtained that show thermotropic smectic A phases over a temperature range of 198 to 260°C. The complexes [PdClL A]2 and [PdClLB]2 can be transformed into a variety of mixed-ligand PdII complexes by treatment with salicyl-aldimine p-C12H25O(C6H 4)COO(C6H3)(OH)CH=N(C6H 4)-Fcph (LCH) and β-aminovinyl ketone p-C 12H25O(C6H4)-COCH=CHNH(C 6H4)Fcph (LDH). The obtained mixed-ligand heterometallic complexes [PdLALC], [PdLBLC], [PdLALD] and [PdLBLD] exhibit enantiotropic, thermotropic nematic phases over a broad temperature range from 71 to 205°C. The structures of the synthesized compounds were characterized by means of 1H NMR, IR and UV spectroscopy, as well as elemental analysis. The liquid crystalline properties were studied by polarising optical microscopy and DSC.",
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A novel series of heteropolynuclear metallomesogens : Organopalladium complexes with ferrocenophane-containing ligands. / Kadkin, Oleg N.; An, Jaein; Han, Haksoo; Galyametdinov, Yuri G.

In: European Journal of Inorganic Chemistry, No. 10, 01.04.2008, p. 1682-1688.

Research output: Contribution to journalArticle

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T1 - A novel series of heteropolynuclear metallomesogens

T2 - Organopalladium complexes with ferrocenophane-containing ligands

AU - Kadkin, Oleg N.

AU - An, Jaein

AU - Han, Haksoo

AU - Galyametdinov, Yuri G.

PY - 2008/4/1

Y1 - 2008/4/1

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AB - Ferrocenophane-containing (Fcph) Schiff's bases p-C12H 25O-(C6H4)CH=N(C6H4)Fcph (LAH) and p-C12H25O(C6H 4)COO-(C6H4)CH=N(C6H 4)Fcph (LBH) react with palladium(II) acetate to form μ-acetato- and chloro-bridged dimeric organo-palladium complexes. By exchanging acetato-groups with the chloride anions, μ-chloro-bridged heteropolynuclear dimers are obtained that show thermotropic smectic A phases over a temperature range of 198 to 260°C. The complexes [PdClL A]2 and [PdClLB]2 can be transformed into a variety of mixed-ligand PdII complexes by treatment with salicyl-aldimine p-C12H25O(C6H 4)COO(C6H3)(OH)CH=N(C6H 4)-Fcph (LCH) and β-aminovinyl ketone p-C 12H25O(C6H4)-COCH=CHNH(C 6H4)Fcph (LDH). The obtained mixed-ligand heterometallic complexes [PdLALC], [PdLBLC], [PdLALD] and [PdLBLD] exhibit enantiotropic, thermotropic nematic phases over a broad temperature range from 71 to 205°C. The structures of the synthesized compounds were characterized by means of 1H NMR, IR and UV spectroscopy, as well as elemental analysis. The liquid crystalline properties were studied by polarising optical microscopy and DSC.

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