A simple route for preparing Au/mesoporous silica yolk/shell particles for Au-catalyzed reactions

Young Geon Song, Hochan Chang, Kangtaek Lee

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

We present a simple route to prepare mesoporous hollow silica particles containing an Au core, i.e., yolk/shell particles, by sol-gel and selective etching processes. Using tetraethoxysilane as a silica precursor, zinc acetate as a base catalyst, and cetyltrimethylammonium chloride as a soft template in the presence of Au nanoparticles, double-layered mesoporous shells were produced in one step. Elemental analysis showed that the inner shell consists of zinc silicate and the outer shell is pure silica. Au/mesoporous silica yolk/shell nanoparticles were obtained by selective etching of the zinc oxide phase with citrate buffer. The particle structure and composition were studied by transmission electron microscopy with energy disperse spectroscopy, UV-vis spectroscopy, X-ray diffraction, and nitrogen sorption experiments. Formation of double shells on the Au core in a single step was explained by a difference in the formation rates of the silica and zinc silicate phases. Au/mesoporous yolk/shell particles showed a high catalytic activity for reduction of 4-nitrophenol.

Original languageEnglish
Pages (from-to)1930-1935
Number of pages6
JournalKorean Journal of Chemical Engineering
Volume34
Issue number7
DOIs
Publication statusPublished - 2017 Jul 1

Fingerprint

Silicon Dioxide
Silica
Zinc
Silicates
Etching
Zinc Acetate
Nanoparticles
Zinc Oxide
Zinc oxide
Ultraviolet spectroscopy
Chemical analysis
Citric Acid
Particles (particulate matter)
Sol-gels
Sorption
Catalyst activity
Buffers
Nitrogen
Spectroscopy
Transmission electron microscopy

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

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abstract = "We present a simple route to prepare mesoporous hollow silica particles containing an Au core, i.e., yolk/shell particles, by sol-gel and selective etching processes. Using tetraethoxysilane as a silica precursor, zinc acetate as a base catalyst, and cetyltrimethylammonium chloride as a soft template in the presence of Au nanoparticles, double-layered mesoporous shells were produced in one step. Elemental analysis showed that the inner shell consists of zinc silicate and the outer shell is pure silica. Au/mesoporous silica yolk/shell nanoparticles were obtained by selective etching of the zinc oxide phase with citrate buffer. The particle structure and composition were studied by transmission electron microscopy with energy disperse spectroscopy, UV-vis spectroscopy, X-ray diffraction, and nitrogen sorption experiments. Formation of double shells on the Au core in a single step was explained by a difference in the formation rates of the silica and zinc silicate phases. Au/mesoporous yolk/shell particles showed a high catalytic activity for reduction of 4-nitrophenol.",
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A simple route for preparing Au/mesoporous silica yolk/shell particles for Au-catalyzed reactions. / Song, Young Geon; Chang, Hochan; Lee, Kangtaek.

In: Korean Journal of Chemical Engineering, Vol. 34, No. 7, 01.07.2017, p. 1930-1935.

Research output: Contribution to journalArticle

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