A Single-Step Synthesis of Electroactive Mesoporous ProDOT-Silica Structures

Jeonghun Kim, Byeonggwan Kim, Chokkalingam Anand, Ajayan Mano, Javaid S.M. Zaidi, Katsuhiko Ariga, Jungmok You, Ajayan Vinu, Eunkyoung Kim

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

The single-step preparation of highly ordered mesoporous silica hybrid nanocomposites with conjugated polymers was explored using a novel cationic 3,4-propylenedioxythiophene (ProDOT) surfactant (PrS). The method does not require higherature calcination or a washing procedure. The combination of self-assembly of the silica surfactant and insitu polymerization of the ProDOT tail is responsible for creation of the mesoporosity with ultralarge pores, large pore volume, and electroactivity. As this novel material exhibits excellent textural parameters together with electrical conductivity, we believe that this could find potential applications in various fields. This novel concept of creating mesoporosity without a calcination process is a significant breakthrough in the field of mesoporous materials and the method can be further generalized as a rational preparation of various mesoporous hybrid materials having different structures and pore diameters.

Original languageEnglish
Pages (from-to)8407-8410
Number of pages4
JournalAngewandte Chemie - International Edition
Volume54
Issue number29
DOIs
Publication statusPublished - 2015 Jul 13

Fingerprint

Mesoporous materials
Surface-Active Agents
Silicon Dioxide
Calcination
Surface active agents
Silica
Hybrid materials
Conjugated polymers
Washing
Self assembly
Nanocomposites
Polymerization
poly(3,4-propylenedioxythiophene)
Electric Conductivity

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Kim, Jeonghun ; Kim, Byeonggwan ; Anand, Chokkalingam ; Mano, Ajayan ; Zaidi, Javaid S.M. ; Ariga, Katsuhiko ; You, Jungmok ; Vinu, Ajayan ; Kim, Eunkyoung. / A Single-Step Synthesis of Electroactive Mesoporous ProDOT-Silica Structures. In: Angewandte Chemie - International Edition. 2015 ; Vol. 54, No. 29. pp. 8407-8410.
@article{20b3179b391e4d04887a604268a5e92b,
title = "A Single-Step Synthesis of Electroactive Mesoporous ProDOT-Silica Structures",
abstract = "The single-step preparation of highly ordered mesoporous silica hybrid nanocomposites with conjugated polymers was explored using a novel cationic 3,4-propylenedioxythiophene (ProDOT) surfactant (PrS). The method does not require higherature calcination or a washing procedure. The combination of self-assembly of the silica surfactant and insitu polymerization of the ProDOT tail is responsible for creation of the mesoporosity with ultralarge pores, large pore volume, and electroactivity. As this novel material exhibits excellent textural parameters together with electrical conductivity, we believe that this could find potential applications in various fields. This novel concept of creating mesoporosity without a calcination process is a significant breakthrough in the field of mesoporous materials and the method can be further generalized as a rational preparation of various mesoporous hybrid materials having different structures and pore diameters.",
author = "Jeonghun Kim and Byeonggwan Kim and Chokkalingam Anand and Ajayan Mano and Zaidi, {Javaid S.M.} and Katsuhiko Ariga and Jungmok You and Ajayan Vinu and Eunkyoung Kim",
year = "2015",
month = "7",
day = "13",
doi = "10.1002/anie.201502498",
language = "English",
volume = "54",
pages = "8407--8410",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "29",

}

Kim, J, Kim, B, Anand, C, Mano, A, Zaidi, JSM, Ariga, K, You, J, Vinu, A & Kim, E 2015, 'A Single-Step Synthesis of Electroactive Mesoporous ProDOT-Silica Structures', Angewandte Chemie - International Edition, vol. 54, no. 29, pp. 8407-8410. https://doi.org/10.1002/anie.201502498

A Single-Step Synthesis of Electroactive Mesoporous ProDOT-Silica Structures. / Kim, Jeonghun; Kim, Byeonggwan; Anand, Chokkalingam; Mano, Ajayan; Zaidi, Javaid S.M.; Ariga, Katsuhiko; You, Jungmok; Vinu, Ajayan; Kim, Eunkyoung.

In: Angewandte Chemie - International Edition, Vol. 54, No. 29, 13.07.2015, p. 8407-8410.

Research output: Contribution to journalArticle

TY - JOUR

T1 - A Single-Step Synthesis of Electroactive Mesoporous ProDOT-Silica Structures

AU - Kim, Jeonghun

AU - Kim, Byeonggwan

AU - Anand, Chokkalingam

AU - Mano, Ajayan

AU - Zaidi, Javaid S.M.

AU - Ariga, Katsuhiko

AU - You, Jungmok

AU - Vinu, Ajayan

AU - Kim, Eunkyoung

PY - 2015/7/13

Y1 - 2015/7/13

N2 - The single-step preparation of highly ordered mesoporous silica hybrid nanocomposites with conjugated polymers was explored using a novel cationic 3,4-propylenedioxythiophene (ProDOT) surfactant (PrS). The method does not require higherature calcination or a washing procedure. The combination of self-assembly of the silica surfactant and insitu polymerization of the ProDOT tail is responsible for creation of the mesoporosity with ultralarge pores, large pore volume, and electroactivity. As this novel material exhibits excellent textural parameters together with electrical conductivity, we believe that this could find potential applications in various fields. This novel concept of creating mesoporosity without a calcination process is a significant breakthrough in the field of mesoporous materials and the method can be further generalized as a rational preparation of various mesoporous hybrid materials having different structures and pore diameters.

AB - The single-step preparation of highly ordered mesoporous silica hybrid nanocomposites with conjugated polymers was explored using a novel cationic 3,4-propylenedioxythiophene (ProDOT) surfactant (PrS). The method does not require higherature calcination or a washing procedure. The combination of self-assembly of the silica surfactant and insitu polymerization of the ProDOT tail is responsible for creation of the mesoporosity with ultralarge pores, large pore volume, and electroactivity. As this novel material exhibits excellent textural parameters together with electrical conductivity, we believe that this could find potential applications in various fields. This novel concept of creating mesoporosity without a calcination process is a significant breakthrough in the field of mesoporous materials and the method can be further generalized as a rational preparation of various mesoporous hybrid materials having different structures and pore diameters.

UR - http://www.scopus.com/inward/record.url?scp=84947754638&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84947754638&partnerID=8YFLogxK

U2 - 10.1002/anie.201502498

DO - 10.1002/anie.201502498

M3 - Article

AN - SCOPUS:84947754638

VL - 54

SP - 8407

EP - 8410

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 29

ER -