A study of high pretilt angle generation in nematic liquid crystal (5CB) on rubbed polythiophene surfaces with alkyl chain lengths

Dae Shik Seo, Shunsuke Kobayashi, Michinori Nishikawa, Yoshikazu Yabe

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

High pretilt angles in nematic liquid crystals (NLC) have been generated on rubbed polythiophene (PTP) surfaces with different alkyl chain lengths. The pretilt angle of the NLC, 4-n-pentyl-4′-cyanobiphenyl (5CB), was observed on unidirectionally rubbed PTP surfaces with alkyl chains with more than 9 carbon atoms. We obtained pretilt angle of 15-40° on rubbed PTP surfaces with 10 carbon atoms in the alkyl chain. Also, the pretilt angles of 65-80° of 5CB were obtained on rubbed PTP surfaces with 11 and 12 carbon atoms in the alkyl chain. We suggest that this high pretilt angle generation in 5CB is due to the surface-excluded volume effect by the alkyl chain lengths between the LCs and the PTP surfaces. Finally, we conclude the odd-even effect on rubbed PTP surfaces is clearly contributed to the pretilt angle generation.

Original languageEnglish
Pages (from-to)3531-3532
Number of pages2
JournalJapanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers
Volume35
Issue number6 SUPPL. A
Publication statusPublished - 1996 Jun 1

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Nematic liquid crystals
Chain length
liquid crystals
Polymers
Atoms
Carbon
carbon 12
atoms
carbon

All Science Journal Classification (ASJC) codes

  • Engineering(all)
  • Physics and Astronomy(all)

Cite this

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abstract = "High pretilt angles in nematic liquid crystals (NLC) have been generated on rubbed polythiophene (PTP) surfaces with different alkyl chain lengths. The pretilt angle of the NLC, 4-n-pentyl-4′-cyanobiphenyl (5CB), was observed on unidirectionally rubbed PTP surfaces with alkyl chains with more than 9 carbon atoms. We obtained pretilt angle of 15-40° on rubbed PTP surfaces with 10 carbon atoms in the alkyl chain. Also, the pretilt angles of 65-80° of 5CB were obtained on rubbed PTP surfaces with 11 and 12 carbon atoms in the alkyl chain. We suggest that this high pretilt angle generation in 5CB is due to the surface-excluded volume effect by the alkyl chain lengths between the LCs and the PTP surfaces. Finally, we conclude the odd-even effect on rubbed PTP surfaces is clearly contributed to the pretilt angle generation.",
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A study of high pretilt angle generation in nematic liquid crystal (5CB) on rubbed polythiophene surfaces with alkyl chain lengths. / Seo, Dae Shik; Kobayashi, Shunsuke; Nishikawa, Michinori; Yabe, Yoshikazu.

In: Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers, Vol. 35, No. 6 SUPPL. A, 01.06.1996, p. 3531-3532.

Research output: Contribution to journalArticle

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T1 - A study of high pretilt angle generation in nematic liquid crystal (5CB) on rubbed polythiophene surfaces with alkyl chain lengths

AU - Seo, Dae Shik

AU - Kobayashi, Shunsuke

AU - Nishikawa, Michinori

AU - Yabe, Yoshikazu

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N2 - High pretilt angles in nematic liquid crystals (NLC) have been generated on rubbed polythiophene (PTP) surfaces with different alkyl chain lengths. The pretilt angle of the NLC, 4-n-pentyl-4′-cyanobiphenyl (5CB), was observed on unidirectionally rubbed PTP surfaces with alkyl chains with more than 9 carbon atoms. We obtained pretilt angle of 15-40° on rubbed PTP surfaces with 10 carbon atoms in the alkyl chain. Also, the pretilt angles of 65-80° of 5CB were obtained on rubbed PTP surfaces with 11 and 12 carbon atoms in the alkyl chain. We suggest that this high pretilt angle generation in 5CB is due to the surface-excluded volume effect by the alkyl chain lengths between the LCs and the PTP surfaces. Finally, we conclude the odd-even effect on rubbed PTP surfaces is clearly contributed to the pretilt angle generation.

AB - High pretilt angles in nematic liquid crystals (NLC) have been generated on rubbed polythiophene (PTP) surfaces with different alkyl chain lengths. The pretilt angle of the NLC, 4-n-pentyl-4′-cyanobiphenyl (5CB), was observed on unidirectionally rubbed PTP surfaces with alkyl chains with more than 9 carbon atoms. We obtained pretilt angle of 15-40° on rubbed PTP surfaces with 10 carbon atoms in the alkyl chain. Also, the pretilt angles of 65-80° of 5CB were obtained on rubbed PTP surfaces with 11 and 12 carbon atoms in the alkyl chain. We suggest that this high pretilt angle generation in 5CB is due to the surface-excluded volume effect by the alkyl chain lengths between the LCs and the PTP surfaces. Finally, we conclude the odd-even effect on rubbed PTP surfaces is clearly contributed to the pretilt angle generation.

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