A study on effect of hydrogen reduction reaction on the initial stage of Ni electrodeposition using EQCM

Ki Deok Song; Kwang Bum Kim; Seong Ho Han; Hong Ke Lee

doi:10.1016/S1388-2481(03)00105-X

A study on effect of hydrogen reduction reaction on the initial stage of Ni electrodeposition using EQCM

Ki Deok Song, Kwang Bum Kim, Seong Ho Han, Hong Ke Lee

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Electrodeposition of Ni from acidic sulfate solution with/without the addition of boric acid was studied by electrochemical quartz crystal microbalance (EQCM) to further investigate the initial stage of Ni deposition. EQCM analysis showed that nickel hydroxide was formed due to the pH increase near the electrode caused by hydrogen evolution in the absence of boric acid. In the presence of boric acid, nickel hydride was formed. EQCM was found to be a useful in-situ tool for investigating the effects of the evolution and absorption of hydrogen on metal deposition and separating the charge used for Ni deposition and for hydrogen reduction.

Original language	English
Pages (from-to)	460-466
Number of pages	7
Journal	Electrochemistry Communications
Volume	5
Issue number	6
DOIs	https://doi.org/10.1016/S1388-2481(03)00105-X
Publication status	Published - 2003 Jun 1

Bibliographical note

Funding Information:
This research was supported by Project on Industry Infra-Construction 2002 from the Ministry of Commerce, Industry and Energy of Republic of Korea.

All Science Journal Classification (ASJC) codes

Electrochemistry

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10.1016/S1388-2481(03)00105-X

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abstract = "Electrodeposition of Ni from acidic sulfate solution with/without the addition of boric acid was studied by electrochemical quartz crystal microbalance (EQCM) to further investigate the initial stage of Ni deposition. EQCM analysis showed that nickel hydroxide was formed due to the pH increase near the electrode caused by hydrogen evolution in the absence of boric acid. In the presence of boric acid, nickel hydride was formed. EQCM was found to be a useful in-situ tool for investigating the effects of the evolution and absorption of hydrogen on metal deposition and separating the charge used for Ni deposition and for hydrogen reduction.",

author = "Song, {Ki Deok} and Kim, {Kwang Bum} and Han, {Seong Ho} and Lee, {Hong Ke}",

note = "Funding Information: This research was supported by Project on Industry Infra-Construction 2002 from the Ministry of Commerce, Industry and Energy of Republic of Korea.",

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AU - Song, Ki Deok

AU - Kim, Kwang Bum

AU - Han, Seong Ho

AU - Lee, Hong Ke

N1 - Funding Information: This research was supported by Project on Industry Infra-Construction 2002 from the Ministry of Commerce, Industry and Energy of Republic of Korea.

PY - 2003/6/1

Y1 - 2003/6/1

N2 - Electrodeposition of Ni from acidic sulfate solution with/without the addition of boric acid was studied by electrochemical quartz crystal microbalance (EQCM) to further investigate the initial stage of Ni deposition. EQCM analysis showed that nickel hydroxide was formed due to the pH increase near the electrode caused by hydrogen evolution in the absence of boric acid. In the presence of boric acid, nickel hydride was formed. EQCM was found to be a useful in-situ tool for investigating the effects of the evolution and absorption of hydrogen on metal deposition and separating the charge used for Ni deposition and for hydrogen reduction.

AB - Electrodeposition of Ni from acidic sulfate solution with/without the addition of boric acid was studied by electrochemical quartz crystal microbalance (EQCM) to further investigate the initial stage of Ni deposition. EQCM analysis showed that nickel hydroxide was formed due to the pH increase near the electrode caused by hydrogen evolution in the absence of boric acid. In the presence of boric acid, nickel hydride was formed. EQCM was found to be a useful in-situ tool for investigating the effects of the evolution and absorption of hydrogen on metal deposition and separating the charge used for Ni deposition and for hydrogen reduction.

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A study on effect of hydrogen reduction reaction on the initial stage of Ni electrodeposition using EQCM

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

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