A synthetic route for the preparation of core-shell nanoparticles using a protective carbon layer and ozone treatment

Youngick Cho, Hojin Lee, Yoonjae Jeong, Hansung Kim

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

A novel synthetic process was developed to synthesize nano-sized core-shell catalysts through atomic rearrangement by heat-treatment. Agglomeration of nanoparticles caused by the high-temperature heat-treatment was alleviated by using a modified protective coating method. In this method, the carbon layer formed by the carbonization of polydopamine serves as a protective coating layer, which suppresses the sintering of the catalyst particles continuously until the high-temperature heat-treatment is completed. Later, the carbonized carbon layer is removed by ozone treatment because it blocks the active site of the catalyst. Since ozone is a highly oxidative gas, it can selectively remove the carbon layer at room temperature in just 7 minutes without affecting the physical properties of the catalyst itself, which makes this method suitable for mass production. The Pt-based alloy catalyst was prepared by this unique process was proved to have a Pt-rich shell structure, and the particles can remain small (∼5 nm) even after high-temperature heat-treatment, thus exhibiting high oxygen reduction reaction (ORR) activity in fuel cells.

Original languageEnglish
Pages (from-to)F285-F290
JournalJournal of the Electrochemical Society
Volume165
Issue number5
DOIs
Publication statusPublished - 2018

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

Fingerprint Dive into the research topics of 'A synthetic route for the preparation of core-shell nanoparticles using a protective carbon layer and ozone treatment'. Together they form a unique fingerprint.

  • Cite this