Abstract
A triazole-bearing picket fence type nickel porphyrin (1) has been synthesized as a host compound for anion binding. Among the various anionic species examined, cyanide was the only one that affected a spectral change of 1. Moreover, 1 exhibited strong homotropic positive allosterism against cyanide binding due to an electronic effect as well as multiple hydrogen bonds formed between cyanide and the triazole groups. This journal is
Original language | English |
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Pages (from-to) | 7486-7488 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 51 |
Issue number | 35 |
DOIs | |
Publication status | Published - 2015 May 1 |
Bibliographical note
Publisher Copyright:© The Royal Society of Chemistry 2015.
All Science Journal Classification (ASJC) codes
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry