A triazole-bearing picket fence type nickel porphyrin as a cyanide selective allosteric host

Kyeong Im Hong, Hongsik Yoon, Woo Dong Jang

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

A triazole-bearing picket fence type nickel porphyrin (1) has been synthesized as a host compound for anion binding. Among the various anionic species examined, cyanide was the only one that affected a spectral change of 1. Moreover, 1 exhibited strong homotropic positive allosterism against cyanide binding due to an electronic effect as well as multiple hydrogen bonds formed between cyanide and the triazole groups. This journal is

Original languageEnglish
Pages (from-to)7486-7488
Number of pages3
JournalChemical Communications
Volume51
Issue number35
DOIs
Publication statusPublished - 2015 May 1

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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