A triazole-bearing picket fence type nickel porphyrin as a cyanide selective allosteric host

Kyeong Im Hong; Hongsik Yoon; Woo Dong Jang

doi:10.1039/c5cc00809c

A triazole-bearing picket fence type nickel porphyrin as a cyanide selective allosteric host

Kyeong Im Hong, Hongsik Yoon, Woo Dong Jang

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

A triazole-bearing picket fence type nickel porphyrin (1) has been synthesized as a host compound for anion binding. Among the various anionic species examined, cyanide was the only one that affected a spectral change of 1. Moreover, 1 exhibited strong homotropic positive allosterism against cyanide binding due to an electronic effect as well as multiple hydrogen bonds formed between cyanide and the triazole groups. This journal is

Original language	English
Pages (from-to)	7486-7488
Number of pages	3
Journal	Chemical Communications
Volume	51
Issue number	35
DOIs	https://doi.org/10.1039/c5cc00809c
Publication status	Published - 2015 May 1

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "A triazole-bearing picket fence type nickel porphyrin (1) has been synthesized as a host compound for anion binding. Among the various anionic species examined, cyanide was the only one that affected a spectral change of 1. Moreover, 1 exhibited strong homotropic positive allosterism against cyanide binding due to an electronic effect as well as multiple hydrogen bonds formed between cyanide and the triazole groups. This journal is",

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