A triazole-bearing picket fence type nickel porphyrin as a cyanide selective allosteric host

Kyeong Im Hong, Hongsik Yoon, Woo Dong Jang

Research output: Contribution to journalArticlepeer-review

30 Citations (Scopus)

Abstract

A triazole-bearing picket fence type nickel porphyrin (1) has been synthesized as a host compound for anion binding. Among the various anionic species examined, cyanide was the only one that affected a spectral change of 1. Moreover, 1 exhibited strong homotropic positive allosterism against cyanide binding due to an electronic effect as well as multiple hydrogen bonds formed between cyanide and the triazole groups.

Original languageEnglish
Pages (from-to)7486-7488
Number of pages3
JournalChemical Communications
Volume51
Issue number35
DOIs
Publication statusPublished - 2015 May 1

Bibliographical note

Publisher Copyright:
© The Royal Society of Chemistry 2015.

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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