Abstract
A triazole-bearing picket fence type nickel porphyrin (1) has been synthesized as a host compound for anion binding. Among the various anionic species examined, cyanide was the only one that affected a spectral change of 1. Moreover, 1 exhibited strong homotropic positive allosterism against cyanide binding due to an electronic effect as well as multiple hydrogen bonds formed between cyanide and the triazole groups. This journal is
| Original language | English |
|---|---|
| Pages (from-to) | 7486-7488 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 51 |
| Issue number | 35 |
| DOIs | |
| Publication status | Published - 2015 May 1 |
All Science Journal Classification (ASJC) codes
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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Hong, K. I., Yoon, H., & Jang, W. D. (2015). A triazole-bearing picket fence type nickel porphyrin as a cyanide selective allosteric host. Chemical Communications, 51(35), 7486-7488. https://doi.org/10.1039/c5cc00809c