Abundance of CuZn+ SnZn and 2CuZn +Sn Zn defect clusters in kesterite solar cells

Shiyou Chen, Lin Wang Wang, Aron Walsh, X. G. Gong, Su Huai Wei

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133 Citations (Scopus)

Abstract

Kesterite solar cells show the highest efficiency when the absorber layers (Cu2 ZnSnS4 [CZTS], Cu2 ZnSnSe4 [CZTSe] and their alloys) are non-stoichiometric with Cu / (Zn + Sn) ≈ 0.8 and Zn / Sn ≈ 1.2. The fundamental cause is so far not understood. Using a first-principles theory, we show that passivated defect clusters such as Cu Zn+ SnZn and 2 CuZn+ SnZn have high concentrations even in stoichiometric samples with Cu/(ZnSn) and Zn/Sn ratios near 1. The partially passivated CuZn+ SnZn cluster produces a deep donor level in the band gap of CZTS, and the fully passivated 2CuZn+ SnZn cluster causes a significant band gap decrease. Both effects are detrimental to photovoltaic performance, so Zn-rich and Cu, Sn-poor conditions are required to prevent their formation and increase the efficiency. The donor level is relatively shallower in CZTSe than in CZTS, which gives an explanation to the higher efficiency obtained in Cu2 ZnSn (S, Se)4 (CZTSSe) cells with high Se content.

Original languageEnglish
Article number223901
JournalApplied Physics Letters
Volume101
Issue number22
DOIs
Publication statusPublished - 2012 Nov 26

Bibliographical note

Funding Information:
The work in China was supported by NSF of China (Nos. 61106087 and 10934002), the Special Funds for Major State Basic Research (No. 2012CB921401), the Research Program of Shanghai municipality and MOE, PCSIRT and CC of ECNU. The work (manuscript preparation) performed in JCAP, a DOE Energy Innovation Hub, was supported through the Office of Science of the U.S. DOE under Award No. DE-SC0004993. A.W. acknowledges support from the Royal Society for a University Research Fellowship and EPSRC Grant No. EP/I01330X/1. The work at NREL was funded by the U.S. DOE, under Contract No. DE-AC36-08GO28308.

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy (miscellaneous)

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