Activity coefficient of manganese in copper

Sung Mo Jung, Chang Hee Rhee, Dong Joon Min

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

A slag/metal equilibrium experiment was conducted to derive an equation that correlates the activity coefficient of manganese (Mn) in copper (Cu) to temperature in the process of determining the activity of MnO in slags. The activity of Mn in liquid Cu was measured by equilibrating the Cu with a solid MnO pellet using an Al2O3 crucible in CO-CO2 gas mixture. The activity coefficient of Mn in Cu with respect to liquid Mn was calculated by analyzing Mn in Cu. The metallic Cu separated from a MnO pallet was supplied for the chemical analysis of the Mn by atomic absorption spectroscopy. The linear relationship between the activity and concentration of Mn in Cu was obtained in temperature range from 1623 to 1773K. Experimental investigation showed that the activity coefficient of Mn in Cu and the temperature could be represented by applying the regular solution model to Cu-Mn solution.

Original languageEnglish
Pages (from-to)1699-1701
Number of pages3
JournalISIJ International
Volume47
Issue number11
DOIs
Publication statusPublished - 2007 Dec 1

Fingerprint

Activity coefficients
Manganese
Copper
Slags
Atomic spectroscopy
Pallets
Crucibles
Liquids
Carbon Monoxide
Absorption spectroscopy
Gas mixtures
Temperature
Metals

All Science Journal Classification (ASJC) codes

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

Cite this

Jung, Sung Mo ; Rhee, Chang Hee ; Min, Dong Joon. / Activity coefficient of manganese in copper. In: ISIJ International. 2007 ; Vol. 47, No. 11. pp. 1699-1701.
@article{56ad1ca1a24e4caeb0040fed556ed84e,
title = "Activity coefficient of manganese in copper",
abstract = "A slag/metal equilibrium experiment was conducted to derive an equation that correlates the activity coefficient of manganese (Mn) in copper (Cu) to temperature in the process of determining the activity of MnO in slags. The activity of Mn in liquid Cu was measured by equilibrating the Cu with a solid MnO pellet using an Al2O3 crucible in CO-CO2 gas mixture. The activity coefficient of Mn in Cu with respect to liquid Mn was calculated by analyzing Mn in Cu. The metallic Cu separated from a MnO pallet was supplied for the chemical analysis of the Mn by atomic absorption spectroscopy. The linear relationship between the activity and concentration of Mn in Cu was obtained in temperature range from 1623 to 1773K. Experimental investigation showed that the activity coefficient of Mn in Cu and the temperature could be represented by applying the regular solution model to Cu-Mn solution.",
author = "Jung, {Sung Mo} and Rhee, {Chang Hee} and Min, {Dong Joon}",
year = "2007",
month = "12",
day = "1",
doi = "10.2355/isijinternational.47.1699",
language = "English",
volume = "47",
pages = "1699--1701",
journal = "ISIJ International",
issn = "0915-1559",
publisher = "Iron and Steel Institute of Japan",
number = "11",

}

Activity coefficient of manganese in copper. / Jung, Sung Mo; Rhee, Chang Hee; Min, Dong Joon.

In: ISIJ International, Vol. 47, No. 11, 01.12.2007, p. 1699-1701.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Activity coefficient of manganese in copper

AU - Jung, Sung Mo

AU - Rhee, Chang Hee

AU - Min, Dong Joon

PY - 2007/12/1

Y1 - 2007/12/1

N2 - A slag/metal equilibrium experiment was conducted to derive an equation that correlates the activity coefficient of manganese (Mn) in copper (Cu) to temperature in the process of determining the activity of MnO in slags. The activity of Mn in liquid Cu was measured by equilibrating the Cu with a solid MnO pellet using an Al2O3 crucible in CO-CO2 gas mixture. The activity coefficient of Mn in Cu with respect to liquid Mn was calculated by analyzing Mn in Cu. The metallic Cu separated from a MnO pallet was supplied for the chemical analysis of the Mn by atomic absorption spectroscopy. The linear relationship between the activity and concentration of Mn in Cu was obtained in temperature range from 1623 to 1773K. Experimental investigation showed that the activity coefficient of Mn in Cu and the temperature could be represented by applying the regular solution model to Cu-Mn solution.

AB - A slag/metal equilibrium experiment was conducted to derive an equation that correlates the activity coefficient of manganese (Mn) in copper (Cu) to temperature in the process of determining the activity of MnO in slags. The activity of Mn in liquid Cu was measured by equilibrating the Cu with a solid MnO pellet using an Al2O3 crucible in CO-CO2 gas mixture. The activity coefficient of Mn in Cu with respect to liquid Mn was calculated by analyzing Mn in Cu. The metallic Cu separated from a MnO pallet was supplied for the chemical analysis of the Mn by atomic absorption spectroscopy. The linear relationship between the activity and concentration of Mn in Cu was obtained in temperature range from 1623 to 1773K. Experimental investigation showed that the activity coefficient of Mn in Cu and the temperature could be represented by applying the regular solution model to Cu-Mn solution.

UR - http://www.scopus.com/inward/record.url?scp=38549103640&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=38549103640&partnerID=8YFLogxK

U2 - 10.2355/isijinternational.47.1699

DO - 10.2355/isijinternational.47.1699

M3 - Article

VL - 47

SP - 1699

EP - 1701

JO - ISIJ International

JF - ISIJ International

SN - 0915-1559

IS - 11

ER -