Adsorbent/membrane hybrid (AMH) system for hydrogen separation: Synergy effect between zeolite 5A and silica membrane

Jong Ho Moon, Ji Han Bae, Yun Jin Han, Chang-Ha Lee

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

A hitherto unknown adsorbent/membrane hybrid (AMH) system was developed to enhance the hydrogen separation performance, especially selectivity. The basic idea of this system is to embed zeolite 5A (adsorbent) into a tubular-type methyltriethoxysilane templating silica membrane (MTES membrane) structurally analogous to well-known catalytic-packed membrane reactors. As case studies, transient and pseudo-steady-state permeation/separation performances of AMH system were investigated by using three H2 binary mixtures, H2/CH4, H2/N2 and H2/CO (50:50vol.%). The separation characteristics were ascribed to the molecular size/structure as well as to the adsorption affinity of each molecule due to the mechanisms of steric hindrance, surface diffusion and adsorption equilibrium in the AMH system. In the mixtures which are mainly affected by kinetic separation in the MTES membrane (outside), such as H2/CH4 and H2/N2, the AMH system enhances the H2 selectivity (H2/CH4: 109.8-199.0, H2/N2: 28.2-55.0) owing to synergy effect with the equilibrium separation in an adsorbent bed (inside). Alternatively, in the mixture which is dominated by equilibrium separation in the MTES membrane, such as H2/CO, H2 selectivity of the AMH system (H2/CO: 14.0-32.0) became worse. A rigorous mathematical model, which combined the tubular-type membrane model with the packed adsorption bed model, could successfully predict the transient and pseudo-steady-state permeation/separation in the AMH system.

Original languageEnglish
Pages (from-to)58-69
Number of pages12
JournalJournal of Membrane Science
Volume356
Issue number1-2
DOIs
Publication statusPublished - 2010 Jul 1

Fingerprint

Zeolites
adsorbents
Hybrid systems
Silicon Dioxide
Adsorbents
Hydrogen
Silica
silicon dioxide
membranes
Membranes
hydrogen
Carbon Monoxide
Adsorption
selectivity
Permeation
adsorption
beds
Surface diffusion
surface diffusion
Binary mixtures

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Materials Science(all)
  • Physical and Theoretical Chemistry
  • Filtration and Separation

Cite this

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abstract = "A hitherto unknown adsorbent/membrane hybrid (AMH) system was developed to enhance the hydrogen separation performance, especially selectivity. The basic idea of this system is to embed zeolite 5A (adsorbent) into a tubular-type methyltriethoxysilane templating silica membrane (MTES membrane) structurally analogous to well-known catalytic-packed membrane reactors. As case studies, transient and pseudo-steady-state permeation/separation performances of AMH system were investigated by using three H2 binary mixtures, H2/CH4, H2/N2 and H2/CO (50:50vol.{\%}). The separation characteristics were ascribed to the molecular size/structure as well as to the adsorption affinity of each molecule due to the mechanisms of steric hindrance, surface diffusion and adsorption equilibrium in the AMH system. In the mixtures which are mainly affected by kinetic separation in the MTES membrane (outside), such as H2/CH4 and H2/N2, the AMH system enhances the H2 selectivity (H2/CH4: 109.8-199.0, H2/N2: 28.2-55.0) owing to synergy effect with the equilibrium separation in an adsorbent bed (inside). Alternatively, in the mixture which is dominated by equilibrium separation in the MTES membrane, such as H2/CO, H2 selectivity of the AMH system (H2/CO: 14.0-32.0) became worse. A rigorous mathematical model, which combined the tubular-type membrane model with the packed adsorption bed model, could successfully predict the transient and pseudo-steady-state permeation/separation in the AMH system.",
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Adsorbent/membrane hybrid (AMH) system for hydrogen separation : Synergy effect between zeolite 5A and silica membrane. / Moon, Jong Ho; Bae, Ji Han; Han, Yun Jin; Lee, Chang-Ha.

In: Journal of Membrane Science, Vol. 356, No. 1-2, 01.07.2010, p. 58-69.

Research output: Contribution to journalArticle

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AU - Moon, Jong Ho

AU - Bae, Ji Han

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AU - Lee, Chang-Ha

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