Adsorption Equilibria of Water Vapor on an Alumina/Zeolite 13X Composite and Silica Gel

Hyun Taek Oh, Seung Jun Lim, Jeong Hoon Kim, Chang Ha Lee

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The adsorption equilibria of water vapor on an alumina/zeolite 13X composite and silica gel were measured at 293.15, 303.15, and 313.15 K and at relative pressures (P/Ps) of up to 0.95. The experimental isotherms were compared with those of zeolite 13X and alumina. The data were correlated by the Dubinin-Astakhov (DA) model and the Aranovich-Donohue (AD) model using Sips and Toth isotherms. The heats of adsorption were in the range of 50-59 kJ·mol-1 for silica gel but decreased from 75 to 45 kJ·mol-1 for the alumina/zeolite 13X composite with increased loading. The composite showed much higher adsorption affinities and adsorption amounts than did silica gel in the low-pressure range, owing to the characteristics of zeolite 13X. However, at increased pressures, the isotherm shape for the composite was similar to that for alumina.

Original languageEnglish
Pages (from-to)804-811
Number of pages8
JournalJournal of Chemical and Engineering Data
Volume62
Issue number2
DOIs
Publication statusPublished - 2017 Jan 1

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Zeolites
Aluminum Oxide
Silica Gel
Steam
Silica gel
Water vapor
Alumina
Isotherms
Adsorption
Composite materials

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

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abstract = "The adsorption equilibria of water vapor on an alumina/zeolite 13X composite and silica gel were measured at 293.15, 303.15, and 313.15 K and at relative pressures (P/Ps) of up to 0.95. The experimental isotherms were compared with those of zeolite 13X and alumina. The data were correlated by the Dubinin-Astakhov (DA) model and the Aranovich-Donohue (AD) model using Sips and Toth isotherms. The heats of adsorption were in the range of 50-59 kJ·mol-1 for silica gel but decreased from 75 to 45 kJ·mol-1 for the alumina/zeolite 13X composite with increased loading. The composite showed much higher adsorption affinities and adsorption amounts than did silica gel in the low-pressure range, owing to the characteristics of zeolite 13X. However, at increased pressures, the isotherm shape for the composite was similar to that for alumina.",
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Adsorption Equilibria of Water Vapor on an Alumina/Zeolite 13X Composite and Silica Gel. / Oh, Hyun Taek; Lim, Seung Jun; Kim, Jeong Hoon; Lee, Chang Ha.

In: Journal of Chemical and Engineering Data, Vol. 62, No. 2, 01.01.2017, p. 804-811.

Research output: Contribution to journalArticle

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