Adsorption of light gases in large-pore isoreticular metal organic frameworks

Youn Sang Bae, Andrew Nelson, David Dubbeldam, Houston Frost, Joseph T. Hupp, Randall Q. Snurr

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Metal-organic frameworks (MOF) have emerged as promising materials for separations, gas storage, catalysis, and chemical sensing. One class of widely-studied MOF are the isoreticular metal-organic frameworks (IRMOF), discovered by Yaghi et al. Several large-pore IRMOFs were synthesized by the solvothermal method. Two solvent removal procedures were compared, i.e., the original method involving chloroform exchange suggested by Yaghi and a newly developed procedure. The adsorption properties of light gases, e.g., H2 and CO2, on IRMOF was examined. Grand canonical Monte Carlo simulations of light gases, with and without co-adsorbed solvent molecules, were used to help understand and interpret the experimental results. This is an abstract of a paper presented at the 2007 AIChE Annual Meeting (Salt Lake City, UT 11/4-9/2007).

Original languageEnglish
Title of host publication2007 AIChE Annual Meeting
Publication statusPublished - 2007 Dec 1
Event2007 AIChE Annual Meeting - Salt Lake City, UT, United States
Duration: 2007 Nov 42007 Nov 9

Publication series

Name2007 AIChE Annual Meeting

Other

Other2007 AIChE Annual Meeting
CountryUnited States
CitySalt Lake City, UT
Period07/11/407/11/9

Fingerprint

Adsorption
Gases
Metals
Chloroform
Chlorine compounds
Catalysis
Molecules

All Science Journal Classification (ASJC) codes

  • Biotechnology
  • Chemical Engineering(all)
  • Bioengineering
  • Safety, Risk, Reliability and Quality

Cite this

Bae, Y. S., Nelson, A., Dubbeldam, D., Frost, H., Hupp, J. T., & Snurr, R. Q. (2007). Adsorption of light gases in large-pore isoreticular metal organic frameworks. In 2007 AIChE Annual Meeting (2007 AIChE Annual Meeting).
Bae, Youn Sang ; Nelson, Andrew ; Dubbeldam, David ; Frost, Houston ; Hupp, Joseph T. ; Snurr, Randall Q. / Adsorption of light gases in large-pore isoreticular metal organic frameworks. 2007 AIChE Annual Meeting. 2007. (2007 AIChE Annual Meeting).
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Bae, YS, Nelson, A, Dubbeldam, D, Frost, H, Hupp, JT & Snurr, RQ 2007, Adsorption of light gases in large-pore isoreticular metal organic frameworks. in 2007 AIChE Annual Meeting. 2007 AIChE Annual Meeting, 2007 AIChE Annual Meeting, Salt Lake City, UT, United States, 07/11/4.

Adsorption of light gases in large-pore isoreticular metal organic frameworks. / Bae, Youn Sang; Nelson, Andrew; Dubbeldam, David; Frost, Houston; Hupp, Joseph T.; Snurr, Randall Q.

2007 AIChE Annual Meeting. 2007. (2007 AIChE Annual Meeting).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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Bae YS, Nelson A, Dubbeldam D, Frost H, Hupp JT, Snurr RQ. Adsorption of light gases in large-pore isoreticular metal organic frameworks. In 2007 AIChE Annual Meeting. 2007. (2007 AIChE Annual Meeting).