Advanced Characterization Techniques for Sodium-Ion Battery Studies

Zulipiya Shadike; Enyue Zhao; Yong Ning Zhou; Xiqian Yu; Yong Yang; Enyuan Hu; Seongmin Bak; Lin Gu; Xiao Qing Yang

doi:10.1002/aenm.201702588

Advanced Characterization Techniques for Sodium-Ion Battery Studies

Zulipiya Shadike, Enyue Zhao, Yong Ning Zhou, Xiqian Yu, Yong Yang, Enyuan Hu, Seongmin Bak, Lin Gu, Xiao Qing Yang

Department of Materials Science and Engineering

Research output: Contribution to journal › Review article › peer-review

Abstract

Sodium (Na)-ion batteries (NIBs) are considered promising alternative candidates to the well-commercialized lithium-ion batteries, especially for applications in large-scale energy storage systems. The electrochemical performance of NIBs such as the cyclability, rate capability, and voltage profiles are strongly dependent on the structural and morphological evolution, phase transformation, sodium-ion diffusion, and electrode/electrolyte interface reconstruction during charge–discharge cycling. Therefore, in-depth understanding of the structure and kinetics of electrode materials and the electrode/electrolyte interfaces is essential for optimizing current NIB systems and exploring new materials for NIBs. Recently, rapid progress and development in spectroscopic, microscopic, and scattering techniques have provided extensive insight into the nature of structural evolution, morphological changes of electrode materials, and electrode/electrolyte interface in NIBs. In this review, a comprehensive overview of both static (ex situ) and real-time (in situ or in operando) techniques for studying the NIBs is provided. Special focus is placed on how these techniques are applied to the fundamental investigation of NIB systems and what important results are obtained.

Original language	English
Article number	1702588
Journal	Advanced Energy Materials
Volume	8
Issue number	17
DOIs	https://doi.org/10.1002/aenm.201702588
Publication status	Published - 2018 Jun 15

Bibliographical note

Funding Information:
Leader of the electrochemical energy storage group in the Chemistry Division of Brookhaven National Laboratory (BNL). He is the Principal Investigator (PI) for several Battery Material Research (BMR) programs including the Batter500 con- sortium at BNL funded by the Office of Vehicle Technologies, EE&RE, U.S. Department of Energy (USDOE). He received his B.S. in Material Science from Shannxi Mechanic Engineering Institute in Xi’an, China, in 1976 and Ph.D. in Physics from University of Florida, Gainesville, Florida, USA in 1986. He received the “2012 Vehicle Technologies Program R&D Award” from the Vehicle Technologies Office of EE&RE, USDOE in May, 2012. In January 2015, he received the IBA201 Research award from the International Battery Association (IBA).

Publisher Copyright:
© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

All Science Journal Classification (ASJC) codes

Renewable Energy, Sustainability and the Environment
Materials Science(all)

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1002/aenm.201702588

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title = "Advanced Characterization Techniques for Sodium-Ion Battery Studies",

abstract = "Sodium (Na)-ion batteries (NIBs) are considered promising alternative candidates to the well-commercialized lithium-ion batteries, especially for applications in large-scale energy storage systems. The electrochemical performance of NIBs such as the cyclability, rate capability, and voltage profiles are strongly dependent on the structural and morphological evolution, phase transformation, sodium-ion diffusion, and electrode/electrolyte interface reconstruction during charge–discharge cycling. Therefore, in-depth understanding of the structure and kinetics of electrode materials and the electrode/electrolyte interfaces is essential for optimizing current NIB systems and exploring new materials for NIBs. Recently, rapid progress and development in spectroscopic, microscopic, and scattering techniques have provided extensive insight into the nature of structural evolution, morphological changes of electrode materials, and electrode/electrolyte interface in NIBs. In this review, a comprehensive overview of both static (ex situ) and real-time (in situ or in operando) techniques for studying the NIBs is provided. Special focus is placed on how these techniques are applied to the fundamental investigation of NIB systems and what important results are obtained.",

author = "Zulipiya Shadike and Enyue Zhao and Zhou, {Yong Ning} and Xiqian Yu and Yong Yang and Enyuan Hu and Seongmin Bak and Lin Gu and Yang, {Xiao Qing}",

note = "Funding Information: Leader of the electrochemical energy storage group in the Chemistry Division of Brookhaven National Laboratory (BNL). He is the Principal Investigator (PI) for several Battery Material Research (BMR) programs including the Batter500 con- sortium at BNL funded by the Office of Vehicle Technologies, EE&RE, U.S. Department of Energy (USDOE). He received his B.S. in Material Science from Shannxi Mechanic Engineering Institute in Xi{\textquoteright}an, China, in 1976 and Ph.D. in Physics from University of Florida, Gainesville, Florida, USA in 1986. He received the “2012 Vehicle Technologies Program R&D Award” from the Vehicle Technologies Office of EE&RE, USDOE in May, 2012. In January 2015, he received the IBA201 Research award from the International Battery Association (IBA). Publisher Copyright: {\textcopyright} 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

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AU - Shadike, Zulipiya

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AU - Hu, Enyuan

AU - Bak, Seongmin

AU - Gu, Lin

AU - Yang, Xiao Qing

N1 - Funding Information: Leader of the electrochemical energy storage group in the Chemistry Division of Brookhaven National Laboratory (BNL). He is the Principal Investigator (PI) for several Battery Material Research (BMR) programs including the Batter500 con- sortium at BNL funded by the Office of Vehicle Technologies, EE&RE, U.S. Department of Energy (USDOE). He received his B.S. in Material Science from Shannxi Mechanic Engineering Institute in Xi’an, China, in 1976 and Ph.D. in Physics from University of Florida, Gainesville, Florida, USA in 1986. He received the “2012 Vehicle Technologies Program R&D Award” from the Vehicle Technologies Office of EE&RE, USDOE in May, 2012. In January 2015, he received the IBA201 Research award from the International Battery Association (IBA). Publisher Copyright: © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

PY - 2018/6/15

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N2 - Sodium (Na)-ion batteries (NIBs) are considered promising alternative candidates to the well-commercialized lithium-ion batteries, especially for applications in large-scale energy storage systems. The electrochemical performance of NIBs such as the cyclability, rate capability, and voltage profiles are strongly dependent on the structural and morphological evolution, phase transformation, sodium-ion diffusion, and electrode/electrolyte interface reconstruction during charge–discharge cycling. Therefore, in-depth understanding of the structure and kinetics of electrode materials and the electrode/electrolyte interfaces is essential for optimizing current NIB systems and exploring new materials for NIBs. Recently, rapid progress and development in spectroscopic, microscopic, and scattering techniques have provided extensive insight into the nature of structural evolution, morphological changes of electrode materials, and electrode/electrolyte interface in NIBs. In this review, a comprehensive overview of both static (ex situ) and real-time (in situ or in operando) techniques for studying the NIBs is provided. Special focus is placed on how these techniques are applied to the fundamental investigation of NIB systems and what important results are obtained.

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Advanced Characterization Techniques for Sodium-Ion Battery Studies

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

UN SDGs

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