Advanced Oxidation Processes. Description of a Kinetic Model for the Oxidation of Hazardous Materials in Aqueous Media with Ozone and Hydrogen Peroxide in a Semibatch Reactor

William H. Glaze, Joon wun Kang

Research output: Contribution to journalArticle

269 Citations (Scopus)

Abstract

A model is presented that describes the kinetics of the oxidation of micropollutants in water with the combination of ozone and hydrogen peroxide in a sparged, semibatch reactor. The model is based on known reactions of the 03/H202system plus mass-transfer characteristics of the reactor. The principal kinetic species for micropollutant oxidation is assumed to be the hydroxyl radical. The model is tested and validated in distilled water spiked with an excess of bicarbonate, a known hydroxyl radical scavenger.

Original languageEnglish
Pages (from-to)1573-1580
Number of pages8
JournalIndustrial and Engineering Chemistry Research
Volume28
Issue number11
DOIs
Publication statusPublished - 1989 Nov 1

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Industrial and Manufacturing Engineering

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