Advanced Oxidation Processes. Description of a Kinetic Model for the Oxidation of Hazardous Materials in Aqueous Media with Ozone and Hydrogen Peroxide in a Semibatch Reactor

William H. Glaze, Joonwun Kang

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267 Citations (Scopus)

Abstract

A model is presented that describes the kinetics of the oxidation of micropollutants in water with the combination of ozone and hydrogen peroxide in a sparged, semibatch reactor. The model is based on known reactions of the 03/H202system plus mass-transfer characteristics of the reactor. The principal kinetic species for micropollutant oxidation is assumed to be the hydroxyl radical. The model is tested and validated in distilled water spiked with an excess of bicarbonate, a known hydroxyl radical scavenger.

Original languageEnglish
Pages (from-to)1573-1580
Number of pages8
JournalIndustrial and Engineering Chemistry Research
Volume28
Issue number11
DOIs
Publication statusPublished - 1989 Nov 1

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Hazardous Substances
Hazardous materials
Ozone
Hydrogen peroxide
Hydrogen Peroxide
Hydroxyl Radical
Oxidation
Kinetics
Water
Bicarbonates
Mass transfer

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Industrial and Manufacturing Engineering

Cite this

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