Alkali resistant Ni-loaded yolk-shell catalysts for direct internal reforming in molten carbonate fuel cells

Won Jun Jang, Young Jun Hong, Hak Min Kim, Jae Oh Shim, Hyun Seog Roh, Yun Chan Kang

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

A facile and scalable spray pyrolysis process is applied to synthesize multi-shelled Ni-loaded yolk-shell catalysts on various supports (Al2O3, CeO2, ZrO2, and La(OH)3). The prepared catalysts are applied to direct internal reforming (DIR) in a molten carbonate fuel cell (MCFC). Even on exposure to alkali hydroxide vapors, the Ni-loaded yolk-shell catalysts remain highly active for DIR-MCFCs. The Ni@Al2O3 microspheres show the highest conversion (92%) of CH4 and the best stability among the prepared Ni-loaded yolk-shell catalysts. Although the initial CH4 conversion of the Ni@ZrO2 microspheres is higher than that of the Ni@CeO2 microspheres, the Ni@CeO2 microspheres are more stable. The catalytic performance is strongly dependent on the surface area and acidity and also partly dependent on the reducibility. The acidic nature of Al2O3 combined with its high surface area and yolk-shell structure enhances the adsorption of CH4 and resistance against alkali poisoning, resulting in efficient DIR-MCFC reactions.

Original languageEnglish
Pages (from-to)1-8
Number of pages8
JournalJournal of Power Sources
Volume352
DOIs
Publication statusPublished - 2017 Jan 1

Fingerprint

molten carbonate fuel cells
Molten carbonate fuel cells (MCFC)
Alkalies
Reforming reactions
Microspheres
alkalies
catalysts
Catalysts
Spray pyrolysis
poisoning
Catalyst supports
Acidity
acidity
hydroxides
pyrolysis
sprayers
Vapors
vapors
Adsorption
adsorption

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering

Cite this

Jang, Won Jun ; Hong, Young Jun ; Kim, Hak Min ; Shim, Jae Oh ; Roh, Hyun Seog ; Kang, Yun Chan. / Alkali resistant Ni-loaded yolk-shell catalysts for direct internal reforming in molten carbonate fuel cells. In: Journal of Power Sources. 2017 ; Vol. 352. pp. 1-8.
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Alkali resistant Ni-loaded yolk-shell catalysts for direct internal reforming in molten carbonate fuel cells. / Jang, Won Jun; Hong, Young Jun; Kim, Hak Min; Shim, Jae Oh; Roh, Hyun Seog; Kang, Yun Chan.

In: Journal of Power Sources, Vol. 352, 01.01.2017, p. 1-8.

Research output: Contribution to journalArticle

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AU - Hong, Young Jun

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AU - Kang, Yun Chan

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AB - A facile and scalable spray pyrolysis process is applied to synthesize multi-shelled Ni-loaded yolk-shell catalysts on various supports (Al2O3, CeO2, ZrO2, and La(OH)3). The prepared catalysts are applied to direct internal reforming (DIR) in a molten carbonate fuel cell (MCFC). Even on exposure to alkali hydroxide vapors, the Ni-loaded yolk-shell catalysts remain highly active for DIR-MCFCs. The Ni@Al2O3 microspheres show the highest conversion (92%) of CH4 and the best stability among the prepared Ni-loaded yolk-shell catalysts. Although the initial CH4 conversion of the Ni@ZrO2 microspheres is higher than that of the Ni@CeO2 microspheres, the Ni@CeO2 microspheres are more stable. The catalytic performance is strongly dependent on the surface area and acidity and also partly dependent on the reducibility. The acidic nature of Al2O3 combined with its high surface area and yolk-shell structure enhances the adsorption of CH4 and resistance against alkali poisoning, resulting in efficient DIR-MCFC reactions.

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