All-solution-processed foldable transparent electrodes of Ag nanowire mesh and metal matrix films for flexible electronics

Ross E. Triambulo, Hahn Gil Cheong, Jin Woo Park

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

In this study, we developed foldable transparent electrodes composed of Ag nanowire (AgNW) networks welded by Ag nanoparticles (AgNPs) reduced from commercial Ag ink. All the processes used were solution-based. Using the Meyer rod method, uniform AgNW networks were roll-to-roll coated on large-area polymer substrates, and the spin-coated AgNPs firmly welded the AgNWs together at junctions and to substrates. The hybrid films consisting of AgNWs and the Ag film matrix exhibited higher electrical conductivity (5.0-7.3 × 10 5 S/m) than and equivalent transparency (90-95%) to the AgNW networks. Furthermore, the hybrid films showed significantly better bending stability than AgNW networks. During cyclic bending tests to 10,000 cycles at 5 mm bending radius and even when almost folded with rb of 1 mm, the resistivity changes were negligible because AgNWs were tightly held and adhered to the substrate by Ag films covering wires, thereby hindering fracturing of AgNWs under tension. Because the films were fabricated at a low temperature, there was no oxidation on the surfaces of the films. Hence, flexible organic light-emitting diodes (f-OLEDs) were successfully fabricated on polyethylene terephthalates (PET) coated with the hybrid films. The f-OLED in the bent state was comparable to that in the flat state, validating the potential applications of these transparent hybrid films as electrodes in various flexible electronics.

Original languageEnglish
Pages (from-to)2685-2695
Number of pages11
JournalOrganic Electronics
Volume15
Issue number11
DOIs
Publication statusPublished - 2014 Nov

Fingerprint

Flexible electronics
Nanowires
mesh
nanowires
Metals
Electrodes
electrodes
matrices
electronics
metals
Organic light emitting diodes (OLED)
Substrates
light emitting diodes
Nanoparticles
nanoparticles
electrical resistivity
Polyethylene Terephthalates
fracturing
polyethylene terephthalate
Bending tests

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Biomaterials
  • Chemistry(all)
  • Condensed Matter Physics
  • Materials Chemistry
  • Electrical and Electronic Engineering

Cite this

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title = "All-solution-processed foldable transparent electrodes of Ag nanowire mesh and metal matrix films for flexible electronics",
abstract = "In this study, we developed foldable transparent electrodes composed of Ag nanowire (AgNW) networks welded by Ag nanoparticles (AgNPs) reduced from commercial Ag ink. All the processes used were solution-based. Using the Meyer rod method, uniform AgNW networks were roll-to-roll coated on large-area polymer substrates, and the spin-coated AgNPs firmly welded the AgNWs together at junctions and to substrates. The hybrid films consisting of AgNWs and the Ag film matrix exhibited higher electrical conductivity (5.0-7.3 × 10 5 S/m) than and equivalent transparency (90-95{\%}) to the AgNW networks. Furthermore, the hybrid films showed significantly better bending stability than AgNW networks. During cyclic bending tests to 10,000 cycles at 5 mm bending radius and even when almost folded with rb of 1 mm, the resistivity changes were negligible because AgNWs were tightly held and adhered to the substrate by Ag films covering wires, thereby hindering fracturing of AgNWs under tension. Because the films were fabricated at a low temperature, there was no oxidation on the surfaces of the films. Hence, flexible organic light-emitting diodes (f-OLEDs) were successfully fabricated on polyethylene terephthalates (PET) coated with the hybrid films. The f-OLED in the bent state was comparable to that in the flat state, validating the potential applications of these transparent hybrid films as electrodes in various flexible electronics.",
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All-solution-processed foldable transparent electrodes of Ag nanowire mesh and metal matrix films for flexible electronics. / Triambulo, Ross E.; Cheong, Hahn Gil; Park, Jin Woo.

In: Organic Electronics, Vol. 15, No. 11, 11.2014, p. 2685-2695.

Research output: Contribution to journalArticle

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