Alteration of the solubility of 4,4′-hexafluoroisopropylidene diphtalic anhydride-4,4-oxydianline polyimide by experimental and theoretical methods

Kyoung Yong Chun, Jong Ho Park, Soon Ho Jang, Shul Yong Gun, Yung Il Joe

Research output: Contribution to journalArticle

Abstract

Alteration of the solubility of 4,4′-Hexafluoroisopropylidene diphtalic anhydride-4,4-oxydianline polyimide was investigated through experimental (the solubility experiments and equilibrium swelling) and theoretical (group contribution method by Fedors). In solubility experiments, total solubility obtained by a two dimensional representation (δv vs. δh diagram) was 21.23 (J cm-3) 1/2 . The range of total solubility determined from the equilibrium swelling method was between 22.71 and 22.99 (J cm-3) 1/2 . The total solubility of 6FDA-4,4′ODA polyimide calculated from the group contributions was 22.2 (J cm-3) 1/2 . The difference of solubility is slightly existed between experimental and theoretical method, but showed very good agreement.

Original languageEnglish
Pages (from-to)406-410
Number of pages5
JournalPolymer Journal
Volume32
Issue number5
DOIs
Publication statusPublished - 2000 Jan 1

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Anhydrides
Polyimides
Solubility
Swelling
Experiments

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics
  • Materials Chemistry

Cite this

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title = "Alteration of the solubility of 4,4′-hexafluoroisopropylidene diphtalic anhydride-4,4-oxydianline polyimide by experimental and theoretical methods",
abstract = "Alteration of the solubility of 4,4′-Hexafluoroisopropylidene diphtalic anhydride-4,4-oxydianline polyimide was investigated through experimental (the solubility experiments and equilibrium swelling) and theoretical (group contribution method by Fedors). In solubility experiments, total solubility obtained by a two dimensional representation (δv vs. δh diagram) was 21.23 (J cm-3) 1/2 . The range of total solubility determined from the equilibrium swelling method was between 22.71 and 22.99 (J cm-3) 1/2 . The total solubility of 6FDA-4,4′ODA polyimide calculated from the group contributions was 22.2 (J cm-3) 1/2 . The difference of solubility is slightly existed between experimental and theoretical method, but showed very good agreement.",
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Alteration of the solubility of 4,4′-hexafluoroisopropylidene diphtalic anhydride-4,4-oxydianline polyimide by experimental and theoretical methods. / Chun, Kyoung Yong; Park, Jong Ho; Jang, Soon Ho; Gun, Shul Yong; Joe, Yung Il.

In: Polymer Journal, Vol. 32, No. 5, 01.01.2000, p. 406-410.

Research output: Contribution to journalArticle

TY - JOUR

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AU - Chun, Kyoung Yong

AU - Park, Jong Ho

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AU - Gun, Shul Yong

AU - Joe, Yung Il

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AB - Alteration of the solubility of 4,4′-Hexafluoroisopropylidene diphtalic anhydride-4,4-oxydianline polyimide was investigated through experimental (the solubility experiments and equilibrium swelling) and theoretical (group contribution method by Fedors). In solubility experiments, total solubility obtained by a two dimensional representation (δv vs. δh diagram) was 21.23 (J cm-3) 1/2 . The range of total solubility determined from the equilibrium swelling method was between 22.71 and 22.99 (J cm-3) 1/2 . The total solubility of 6FDA-4,4′ODA polyimide calculated from the group contributions was 22.2 (J cm-3) 1/2 . The difference of solubility is slightly existed between experimental and theoretical method, but showed very good agreement.

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