Anion induced structural transformation in silver-(3,6-dimethoxy-1,2,4,5-tetrazine) coordination polymers under mechanochemical conditions

Philjae Kang, Sooyong Jung, Junhyung Lee, Hye Ji Kang, Hyehee Lee, Moon Gun Choi

Research output: Contribution to journalArticle

7 Citations (Scopus)


Mechanochemical reactions of 3,6-dimethoxy-s-tetrazine (dmotz) with AgCF3SO3 and AgClO4 afforded the 1D linear polymer [Ag(dmotz)(CF3SO3)]n (1) and the 2D grid polymer {[Ag(dmotz)2](ClO4)}n (2), respectively. Mechanochemical processes convert 1 to 2 in the presence of an equivalent of [ClO4]- and dmotz; even on using excess [CF3SO3]-, conversion from 2 to 1 was not observed.

Original languageEnglish
Pages (from-to)11949-11952
Number of pages4
JournalDalton Transactions
Issue number30
Publication statusPublished - 2016 Jan 1


All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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