Anion induced structural transformation in silver-(3,6-dimethoxy-1,2,4,5-tetrazine) coordination polymers under mechanochemical conditions

Philjae Kang, Sooyong Jung, Junhyung Lee, Hye Ji Kang, Hyehee Lee, Moon-Gun Choi

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Mechanochemical reactions of 3,6-dimethoxy-s-tetrazine (dmotz) with AgCF3SO3 and AgClO4 afforded the 1D linear polymer [Ag(dmotz)(CF3SO3)]n (1) and the 2D grid polymer {[Ag(dmotz)2](ClO4)}n (2), respectively. Mechanochemical processes convert 1 to 2 in the presence of an equivalent of [ClO4]- and dmotz; even on using excess [CF3SO3]-, conversion from 2 to 1 was not observed.

Original languageEnglish
Pages (from-to)11949-11952
Number of pages4
JournalDalton Transactions
Volume45
Issue number30
DOIs
Publication statusPublished - 2016 Jan 1

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Silver
Anions
Polymers
perchlorate

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

Cite this

Kang, Philjae ; Jung, Sooyong ; Lee, Junhyung ; Kang, Hye Ji ; Lee, Hyehee ; Choi, Moon-Gun. / Anion induced structural transformation in silver-(3,6-dimethoxy-1,2,4,5-tetrazine) coordination polymers under mechanochemical conditions. In: Dalton Transactions. 2016 ; Vol. 45, No. 30. pp. 11949-11952.
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Anion induced structural transformation in silver-(3,6-dimethoxy-1,2,4,5-tetrazine) coordination polymers under mechanochemical conditions. / Kang, Philjae; Jung, Sooyong; Lee, Junhyung; Kang, Hye Ji; Lee, Hyehee; Choi, Moon-Gun.

In: Dalton Transactions, Vol. 45, No. 30, 01.01.2016, p. 11949-11952.

Research output: Contribution to journalArticle

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