Anion-Templated Self-Assembly of Silver(I) Frameworks Bridged by μ-, μ3-, μ4-1,2,4,5-Tetrazine

Younghun Kim; Philjae Kang; Yonggoon Jeon; Hyeon Mo Cho; Moon Gun Choi

doi:10.1002/bkcs.12182

Anion-Templated Self-Assembly of Silver(I) Frameworks Bridged by μ-, μ₃-, μ₄-1,2,4,5-Tetrazine

Younghun Kim, Philjae Kang, Yonggoon Jeon, Hyeon Mo Cho, Moon Gun Choi

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The formation of Ag(I)-1,2,4,5-tetrazines(ttz) based coordination polymers via the Ag−N coordination and anion−π interactions is described. Coordination-driven self-assembly is a key step to construct coordination polymers, and ttz, an electron-deficient aromatic ring compound, forms interesting anion−π interactions. In this study, a series of silver salts, AgX [X = BF₄, PF₆ and CF₃SO₃ (OTf)], is introduced to determine the influence of shape and size of anions on the formation of coordination polymers, {[Ag(ttz)](BF₄)}_n (1), {[Ag₂(ttz)₃](PF₆)₂}_n (2) and {[Ag₂(ttz)₃(OTf)](OTf)}_n (3). It shows different types of channels in polymers and the coordination modes of ttz (μ, μ₃, and μ₄). The structure of coordination polymers and the influence of anion−π interactions are revealed by single crystal X-ray diffraction. In particular, 3 shows not only the anion−π interaction but also the coordination between the anion and Ag(I) which contributes to the unique framework compared to 1 and 2.

Original language	English
Pages (from-to)	240-244
Number of pages	5
Journal	Bulletin of the Korean Chemical Society
Volume	42
Issue number	2
DOIs	https://doi.org/10.1002/bkcs.12182
Publication status	Published - 2021 Feb

Bibliographical note

Funding Information:
This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (NRF‐2018R1D1A1B07045174). This research was partially supported by the Graduate School of YONSEI University Research Scholarship Grants in 2017.

Publisher Copyright:
© 2020 Korean Chemical Society, Seoul & Wiley-VCH GmbH

All Science Journal Classification (ASJC) codes

Chemistry(all)

Access to Document

10.1002/bkcs.12182

Cite this

@article{5fbe6a48a6cf41fd998fe6695f8448e0,

title = "Anion-Templated Self-Assembly of Silver(I) Frameworks Bridged by μ-, μ3-, μ4-1,2,4,5-Tetrazine",

abstract = "The formation of Ag(I)-1,2,4,5-tetrazines(ttz) based coordination polymers via the Ag−N coordination and anion−π interactions is described. Coordination-driven self-assembly is a key step to construct coordination polymers, and ttz, an electron-deficient aromatic ring compound, forms interesting anion−π interactions. In this study, a series of silver salts, AgX [X = BF4, PF6 and CF3SO3 (OTf)], is introduced to determine the influence of shape and size of anions on the formation of coordination polymers, {[Ag(ttz)](BF4)}n (1), {[Ag2(ttz)3](PF6)2}n (2) and {[Ag2(ttz)3(OTf)](OTf)}n (3). It shows different types of channels in polymers and the coordination modes of ttz (μ, μ3, and μ4). The structure of coordination polymers and the influence of anion−π interactions are revealed by single crystal X-ray diffraction. In particular, 3 shows not only the anion−π interaction but also the coordination between the anion and Ag(I) which contributes to the unique framework compared to 1 and 2.",

author = "Younghun Kim and Philjae Kang and Yonggoon Jeon and Cho, {Hyeon Mo} and Choi, {Moon Gun}",

note = "Funding Information: This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (NRF‐2018R1D1A1B07045174). This research was partially supported by the Graduate School of YONSEI University Research Scholarship Grants in 2017. Publisher Copyright: {\textcopyright} 2020 Korean Chemical Society, Seoul & Wiley-VCH GmbH",

year = "2021",

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AU - Kim, Younghun

AU - Kang, Philjae

AU - Jeon, Yonggoon

AU - Cho, Hyeon Mo

AU - Choi, Moon Gun

N1 - Funding Information: This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (NRF‐2018R1D1A1B07045174). This research was partially supported by the Graduate School of YONSEI University Research Scholarship Grants in 2017. Publisher Copyright: © 2020 Korean Chemical Society, Seoul & Wiley-VCH GmbH

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N2 - The formation of Ag(I)-1,2,4,5-tetrazines(ttz) based coordination polymers via the Ag−N coordination and anion−π interactions is described. Coordination-driven self-assembly is a key step to construct coordination polymers, and ttz, an electron-deficient aromatic ring compound, forms interesting anion−π interactions. In this study, a series of silver salts, AgX [X = BF4, PF6 and CF3SO3 (OTf)], is introduced to determine the influence of shape and size of anions on the formation of coordination polymers, {[Ag(ttz)](BF4)}n (1), {[Ag2(ttz)3](PF6)2}n (2) and {[Ag2(ttz)3(OTf)](OTf)}n (3). It shows different types of channels in polymers and the coordination modes of ttz (μ, μ3, and μ4). The structure of coordination polymers and the influence of anion−π interactions are revealed by single crystal X-ray diffraction. In particular, 3 shows not only the anion−π interaction but also the coordination between the anion and Ag(I) which contributes to the unique framework compared to 1 and 2.

AB - The formation of Ag(I)-1,2,4,5-tetrazines(ttz) based coordination polymers via the Ag−N coordination and anion−π interactions is described. Coordination-driven self-assembly is a key step to construct coordination polymers, and ttz, an electron-deficient aromatic ring compound, forms interesting anion−π interactions. In this study, a series of silver salts, AgX [X = BF4, PF6 and CF3SO3 (OTf)], is introduced to determine the influence of shape and size of anions on the formation of coordination polymers, {[Ag(ttz)](BF4)}n (1), {[Ag2(ttz)3](PF6)2}n (2) and {[Ag2(ttz)3(OTf)](OTf)}n (3). It shows different types of channels in polymers and the coordination modes of ttz (μ, μ3, and μ4). The structure of coordination polymers and the influence of anion−π interactions are revealed by single crystal X-ray diffraction. In particular, 3 shows not only the anion−π interaction but also the coordination between the anion and Ag(I) which contributes to the unique framework compared to 1 and 2.

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