Apple juice and red wine induced mirror-image circular dichroism in quantum dots

Yuri H. Kwon, Shambhavi Tannir, Milan Balaz, Krisztina Varga

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

Juices, wines, and extracts from plants contain high concentrations of various chiral compounds such as carboxylic acids or sugars. Several prior studies reported the synthesis of metallic and semiconducting nanoparticles relying on components of complex biological solutions. Herein, we present preparation of chiral CdS and CdSe quantum dots (QDs) using apple juice and red wine via phase transfer ligand exchange. Although both apple juice and red wine contain a complex mixture of chiral and achiral compounds, we have successfully used them for selective induction of predicted chiroptical properties and confirmed L-malic acid from the apple juice and L-tartaric acid from the red wine as the chiral inducers. This work illustrates the capability of using complex mixtures to construct chiral QDs with desired chiroptical properties as well as potential of QDs to selectively report a chiral molecule in a complex chiral mixture without the need for elaborate chiral recognition system.

Original languageEnglish
Pages (from-to)70-76
Number of pages7
JournalChirality
Volume34
Issue number1
DOIs
Publication statusPublished - 2022 Jan

Bibliographical note

Funding Information:
This work was supported in part by the National Science Foundation (award CBET 1403947; KV, MB), Yonsei University (MB), and the University of New Hampshire (KV). We thank Dr. B. M. Leonard and Dr. N. Arulsamy from University of Wyoming for their assistance with TEM and XRD, respectively. YHK acknowledges support from the Summer Teaching Assistant Fellowship from the University of New Hampshire.

Funding Information:
This work was supported in part by the National Science Foundation (award CBET 1403947; KV, MB), Yonsei University (MB), and the University of New Hampshire (KV). We thank Dr. B. M. Leonard and Dr. N. Arulsamy from University of Wyoming for their assistance with TEM and XRD, respectively. YHK acknowledges support from the Summer Teaching Assistant Fellowship from the University of New Hampshire.

Publisher Copyright:
© 2021 Wiley Periodicals LLC.

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • Catalysis
  • Pharmacology
  • Drug Discovery
  • Spectroscopy
  • Organic Chemistry

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