Aqueous/organic interfacial coordinative crystallization for achieving highly efficient metal-glycine complex crystal growth

Yeong Don Park, Jeong Ho Cho, Hwa Sung Lee

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Highly packed metal ion-organic complex crystals with superior crystalline properties were efficiently obtained using conventional coordination chemistry in a diffusion-controlled growth procedure. This strategy revolved around an aqueous/organic interfacial coordinative crystallization process in which complex crystal growth proceeded at the interface between an organic and an aqueous phase containing the deprotonated glycine and the transition metal ions (Cu(II) and Ag(I)), respectively. The results confirmed that the crystal structures included coordination complexes of the metal ions and the deprotonated glycine, and a new Ag(I)-glycine coordination structure was identified. The strategy demonstrated here provides an efficient synthetic method by which coordination complex crystals may be grown for use in electronic, optical, and bio-related applications.

Original languageEnglish
Pages (from-to)27-31
Number of pages5
JournalJournal of Crystal Growth
Volume346
Issue number1
DOIs
Publication statusPublished - 2012 May 1

Fingerprint

glycine
Crystallization
Crystal growth
Glycine
Metal ions
Amino acids
crystal growth
Metals
Coordination Complexes
crystallization
metal ions
metals
Crystals
Transition metals
Crystal structure
Crystalline materials
crystals
transition metals
chemistry
crystal structure

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

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abstract = "Highly packed metal ion-organic complex crystals with superior crystalline properties were efficiently obtained using conventional coordination chemistry in a diffusion-controlled growth procedure. This strategy revolved around an aqueous/organic interfacial coordinative crystallization process in which complex crystal growth proceeded at the interface between an organic and an aqueous phase containing the deprotonated glycine and the transition metal ions (Cu(II) and Ag(I)), respectively. The results confirmed that the crystal structures included coordination complexes of the metal ions and the deprotonated glycine, and a new Ag(I)-glycine coordination structure was identified. The strategy demonstrated here provides an efficient synthetic method by which coordination complex crystals may be grown for use in electronic, optical, and bio-related applications.",
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Aqueous/organic interfacial coordinative crystallization for achieving highly efficient metal-glycine complex crystal growth. / Park, Yeong Don; Cho, Jeong Ho; Lee, Hwa Sung.

In: Journal of Crystal Growth, Vol. 346, No. 1, 01.05.2012, p. 27-31.

Research output: Contribution to journalArticle

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