Assembled monolayers of hydrophilic particles on water surfaces

Geon Dae Moon, Tae Il Lee, Bongsoo Kim, Geesung Chae, Jinook Kim, Sunghee Kim, Jae Min Myoung, Unyong Jeong

Research output: Contribution to journalArticle

116 Citations (Scopus)

Abstract

A facile and quick approach to prepare self-assembled monolayers of water-dispersible particles on the water surface is presented. Particle suspensions in alcohols were dropped on a water reservoir to form long-range ordered monolayers of various particles, including spherical solid particles, soft hydrogel particles, metal nanoparticles, quantum dots, nanowires, single-wall carbon nanotubes (SWCNTs), nanoplates, and nanosheets. A systematic study was conducted on the variables affecting the monolayer assembly: the solubility parameter of spreading solvents, particle concentration, zeta potential of the particles in the suspension, surface tension of the water phase, hardness of the particles, and addition of a salt in the suspension. This method requires no hydrophobic surface treatment of the particles, which is useful to exploit these monolayer films without changing the native properties of the particles. The study highlights a quick 2D colloidal assembly without cracks in the wafer scale as well as transparent conductive thin films made of SWCNTs and graphenes.

Original languageEnglish
Pages (from-to)8600-8612
Number of pages13
JournalACS Nano
Volume5
Issue number11
DOIs
Publication statusPublished - 2011 Nov 22

Fingerprint

surface water
Particles (particulate matter)
Monolayers
Suspensions
Carbon Nanotubes
Water
Carbon nanotubes
Conductive films
Nanosheets
Metal nanoparticles
Hydrogel
Self assembled monolayers
Zeta potential
Hydrogels
Semiconductor quantum dots
Nanowires
Surface tension
Surface treatment
Alcohols
Solubility

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Engineering(all)
  • Physics and Astronomy(all)

Cite this

Moon, G. D., Lee, T. I., Kim, B., Chae, G., Kim, J., Kim, S., ... Jeong, U. (2011). Assembled monolayers of hydrophilic particles on water surfaces. ACS Nano, 5(11), 8600-8612. https://doi.org/10.1021/nn202733f
Moon, Geon Dae ; Lee, Tae Il ; Kim, Bongsoo ; Chae, Geesung ; Kim, Jinook ; Kim, Sunghee ; Myoung, Jae Min ; Jeong, Unyong. / Assembled monolayers of hydrophilic particles on water surfaces. In: ACS Nano. 2011 ; Vol. 5, No. 11. pp. 8600-8612.
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Moon, GD, Lee, TI, Kim, B, Chae, G, Kim, J, Kim, S, Myoung, JM & Jeong, U 2011, 'Assembled monolayers of hydrophilic particles on water surfaces', ACS Nano, vol. 5, no. 11, pp. 8600-8612. https://doi.org/10.1021/nn202733f

Assembled monolayers of hydrophilic particles on water surfaces. / Moon, Geon Dae; Lee, Tae Il; Kim, Bongsoo; Chae, Geesung; Kim, Jinook; Kim, Sunghee; Myoung, Jae Min; Jeong, Unyong.

In: ACS Nano, Vol. 5, No. 11, 22.11.2011, p. 8600-8612.

Research output: Contribution to journalArticle

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Moon GD, Lee TI, Kim B, Chae G, Kim J, Kim S et al. Assembled monolayers of hydrophilic particles on water surfaces. ACS Nano. 2011 Nov 22;5(11):8600-8612. https://doi.org/10.1021/nn202733f