Balancing light absorptivity and carrier conductivity of graphene quantum dots for high-efficiency bulk heterojunction solar cells

Jung Kyu Kim, Myung Jin Park, Sang Jin Kim, Dong Hwan Wang, Sung Pyo Cho, Sukang Bae, Jong Hyeok Park, Byung Hee Hong

Research output: Contribution to journalArticle

113 Citations (Scopus)

Abstract

Graphene quantum dots (GQDs) have been considered as a novel material because their electronic and optoelectronic properties can be tuned by controlling the size and the functional groups of GQDs. Here we report the synthesis of reduction-controlled GQDs and their application to bulk heterojunction (BHJ) solar cells with enhanced power conversion efficiency (PCE). Three different types of GQDs - graphene oxide quantum dots (GOQDs), 5 h reduced GQDs, and 10 h reduced GQDs - were tested in BHJ solar cells, and the results indicate that GQDs play an important role in increasing optical absorptivity and charge carrier extraction of the BHJ solar cells. The enhanced optical absorptivity by rich functional groups in GOQDs increases short-circuit current, while the improved conductivity of reduced GQDs leads to the increase of fill factors. Thus, the reduction level of GQDs needs to be intermediate to balance the absorptivity and conductivity. Indeed, the partially reduced GQDs yielded the outstandingly improved PCE of 7.60% in BHJ devices compared to a reference device without GQDs (6.70%).

Original languageEnglish
Pages (from-to)7207-7212
Number of pages6
JournalACS Nano
Volume7
Issue number8
DOIs
Publication statusPublished - 2013 Aug 27

    Fingerprint

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Engineering(all)
  • Physics and Astronomy(all)

Cite this