Bis-rhodium hexaphyrins: Metalation of [28]hexaphyrin and a smooth Hückel aromatic-antiaromatic interconversion

Harapriya Rath, Naoki Aratani, Jong Min Lim, Jae Seok Lee, Dongho Kim, Hiroshi Shinokubo, Atsuhiro Osuka

Research output: Contribution to journalArticlepeer-review

19 Citations (Scopus)

Abstract

Metalation of [28]hexaphyrin(1.1.1.1.1.1) with [RhCl(CO)2] 2 resulted in the formation of an antiaromatic bis-Rh(i) complex, which can be oxidized to an aromatic bis-Rh(i) complex with retention of its rectangular structure.

Original languageEnglish
Pages (from-to)3762-3764
Number of pages3
JournalChemical Communications
Issue number25
DOIs
Publication statusPublished - 2009

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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