Bismuth borosilicate-based thick film passivation of Ag grid for large-area dye-sensitized solar cells

Deuk Ho Yeon, Kyung Kon Kim, Nam Gyu Park, Yong Soo Cho

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

A bismuth borosilicate glass-based thick film having a low glass transition temperature of 445°C was investigated as a passivation layer for protecting Ag-grid against corrosive reactions with the common I-/I 3- electrolyte for large area dye-sensitized solar cells (DSSC). Glass paste was carefully screen-printed and then fired in the temperature range of 480°-540°C to have a final thickness of ∼4 μm. The effectiveness of the glass passivation film was related to the degree of densification or porosity, which depended on firing temperature of the glass. A high optical transmittance of ∼70% and the chemical inertness of the well-densified glass film can be highlighted as promising characteristics for this passivation application. The low electrical resistance of ∼27 Ω of the fluorine-doped tin oxide-coated substrate, which was obtained by patterning Ag grid, remained stable over the exposure period of ∼10 days in the electrolyte only when the hermetic protection of Ag was secured by the glass overcoat film after densification at 540°C.

Original languageEnglish
Pages (from-to)1554-1556
Number of pages3
JournalJournal of the American Ceramic Society
Volume93
Issue number6
DOIs
Publication statusPublished - 2010 Jun 1

Fingerprint

Bismuth
Thick films
Passivation
Glass
Densification
Electrolytes
Caustics
Acoustic impedance
Borosilicate glass
Fluorine
Opacity
Ointments
Tin oxides
Porosity
Dye-sensitized solar cells
Temperature
Substrates

All Science Journal Classification (ASJC) codes

  • Ceramics and Composites
  • Materials Chemistry

Cite this

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abstract = "A bismuth borosilicate glass-based thick film having a low glass transition temperature of 445°C was investigated as a passivation layer for protecting Ag-grid against corrosive reactions with the common I-/I 3- electrolyte for large area dye-sensitized solar cells (DSSC). Glass paste was carefully screen-printed and then fired in the temperature range of 480°-540°C to have a final thickness of ∼4 μm. The effectiveness of the glass passivation film was related to the degree of densification or porosity, which depended on firing temperature of the glass. A high optical transmittance of ∼70{\%} and the chemical inertness of the well-densified glass film can be highlighted as promising characteristics for this passivation application. The low electrical resistance of ∼27 Ω of the fluorine-doped tin oxide-coated substrate, which was obtained by patterning Ag grid, remained stable over the exposure period of ∼10 days in the electrolyte only when the hermetic protection of Ag was secured by the glass overcoat film after densification at 540°C.",
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Bismuth borosilicate-based thick film passivation of Ag grid for large-area dye-sensitized solar cells. / Yeon, Deuk Ho; Kim, Kyung Kon; Park, Nam Gyu; Cho, Yong Soo.

In: Journal of the American Ceramic Society, Vol. 93, No. 6, 01.06.2010, p. 1554-1556.

Research output: Contribution to journalArticle

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