Bismuth Islands for Low-Temperature Sodium-Beta Alumina Batteries

Dana Jin, Sangjin Choi, Woosun Jang, Aloysius Soon, Jeongmin Kim, Hongjae Moon, Wooyoung Lee, Younki Lee, Sori Son, Yoon Cheol Park, Heejung Chang, Guosheng Li, Keeyoung Jung, Wooyoung Shim

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Wetting of the liquid metal on the solid electrolyte of a liquid metal battery controls the operating temperature and performance of the battery. Liquid sodium electrodes are particularly attractive because of their low cost, natural abundance, and geological distribution. However, they wet poorly on a solid electrolyte near its melting temperature, limiting their widespread suitability for low-temperature batteries to be used for large-scale energy storage systems. Herein, we develop an isolated metal-island strategy that can improve sodium wetting in sodium-beta alumina batteries that allows operation at lower temperatures. Our results suggest that in situ heat treatment of a solid electrolyte followed by bismuth deposition effectively eliminates oxygen and moisture from the surface of the solid electrolyte, preventing the formation of an oxide layer on the liquid sodium, leading to enhanced wetting. We also show that employing isolated bismuth islands significantly improves cell performance, with cells retaining 94% of their charge after the initial cycle, an improvement over cells without bismuth islands. These results suggest that coating isolated metal islands is a promising and straightforward strategy for the development of low-temperature sodium-β alumina batteries.

Original languageEnglish
Pages (from-to)2917-2924
Number of pages8
JournalACS Applied Materials and Interfaces
Volume11
Issue number3
DOIs
Publication statusPublished - 2019 Jan 23

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Bismuth
Aluminum Oxide
Solid electrolytes
Alumina
Sodium
Wetting
Liquid metals
Temperature
Metal coatings
Liquids
Energy storage
Oxides
Melting point
Moisture
Metals
Heat treatment
Oxygen
Electrodes
Costs

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

Cite this

Jin, Dana ; Choi, Sangjin ; Jang, Woosun ; Soon, Aloysius ; Kim, Jeongmin ; Moon, Hongjae ; Lee, Wooyoung ; Lee, Younki ; Son, Sori ; Park, Yoon Cheol ; Chang, Heejung ; Li, Guosheng ; Jung, Keeyoung ; Shim, Wooyoung. / Bismuth Islands for Low-Temperature Sodium-Beta Alumina Batteries. In: ACS Applied Materials and Interfaces. 2019 ; Vol. 11, No. 3. pp. 2917-2924.
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Jin, D, Choi, S, Jang, W, Soon, A, Kim, J, Moon, H, Lee, W, Lee, Y, Son, S, Park, YC, Chang, H, Li, G, Jung, K & Shim, W 2019, 'Bismuth Islands for Low-Temperature Sodium-Beta Alumina Batteries', ACS Applied Materials and Interfaces, vol. 11, no. 3, pp. 2917-2924. https://doi.org/10.1021/acsami.8b13954

Bismuth Islands for Low-Temperature Sodium-Beta Alumina Batteries. / Jin, Dana; Choi, Sangjin; Jang, Woosun; Soon, Aloysius; Kim, Jeongmin; Moon, Hongjae; Lee, Wooyoung; Lee, Younki; Son, Sori; Park, Yoon Cheol; Chang, Heejung; Li, Guosheng; Jung, Keeyoung; Shim, Wooyoung.

In: ACS Applied Materials and Interfaces, Vol. 11, No. 3, 23.01.2019, p. 2917-2924.

Research output: Contribution to journalArticle

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T1 - Bismuth Islands for Low-Temperature Sodium-Beta Alumina Batteries

AU - Jin, Dana

AU - Choi, Sangjin

AU - Jang, Woosun

AU - Soon, Aloysius

AU - Kim, Jeongmin

AU - Moon, Hongjae

AU - Lee, Wooyoung

AU - Lee, Younki

AU - Son, Sori

AU - Park, Yoon Cheol

AU - Chang, Heejung

AU - Li, Guosheng

AU - Jung, Keeyoung

AU - Shim, Wooyoung

PY - 2019/1/23

Y1 - 2019/1/23

N2 - Wetting of the liquid metal on the solid electrolyte of a liquid metal battery controls the operating temperature and performance of the battery. Liquid sodium electrodes are particularly attractive because of their low cost, natural abundance, and geological distribution. However, they wet poorly on a solid electrolyte near its melting temperature, limiting their widespread suitability for low-temperature batteries to be used for large-scale energy storage systems. Herein, we develop an isolated metal-island strategy that can improve sodium wetting in sodium-beta alumina batteries that allows operation at lower temperatures. Our results suggest that in situ heat treatment of a solid electrolyte followed by bismuth deposition effectively eliminates oxygen and moisture from the surface of the solid electrolyte, preventing the formation of an oxide layer on the liquid sodium, leading to enhanced wetting. We also show that employing isolated bismuth islands significantly improves cell performance, with cells retaining 94% of their charge after the initial cycle, an improvement over cells without bismuth islands. These results suggest that coating isolated metal islands is a promising and straightforward strategy for the development of low-temperature sodium-β alumina batteries.

AB - Wetting of the liquid metal on the solid electrolyte of a liquid metal battery controls the operating temperature and performance of the battery. Liquid sodium electrodes are particularly attractive because of their low cost, natural abundance, and geological distribution. However, they wet poorly on a solid electrolyte near its melting temperature, limiting their widespread suitability for low-temperature batteries to be used for large-scale energy storage systems. Herein, we develop an isolated metal-island strategy that can improve sodium wetting in sodium-beta alumina batteries that allows operation at lower temperatures. Our results suggest that in situ heat treatment of a solid electrolyte followed by bismuth deposition effectively eliminates oxygen and moisture from the surface of the solid electrolyte, preventing the formation of an oxide layer on the liquid sodium, leading to enhanced wetting. We also show that employing isolated bismuth islands significantly improves cell performance, with cells retaining 94% of their charge after the initial cycle, an improvement over cells without bismuth islands. These results suggest that coating isolated metal islands is a promising and straightforward strategy for the development of low-temperature sodium-β alumina batteries.

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