Book-Shaped All-in-One Piezo-Triboelectric Energy Harvester Module with Enhanced Current Characteristics As an Eco-Friendly Energy Source

A book-shaped all-in-one energy harvester module with a piezo-triboelectric hybrid structure as a next-generation eco-friendly energy source was manufactured based on flexible piezoceramic nanofibers with enhanced current characteristics obtained by controlling the added amount of carbon black (CB). To prepare flexible piezoceramic nanofibers with favorable current properties, 0.78Bi_0.5Na_0.5TiO₃−0.22SrTiO₃ (BNT-ST) piezoelectric ceramics were composited with CB, a highly conductive material, and then electrospun with a poly(vinylidene fluorideco–trifluoroethylene) polymer. The prepared CB/BNT-ST nanofibers were modularized into piezoelectric energy harvester modules (PEHMs) with interdigitated electrodes, yielding an improved output performance with a high voltage of 10.1 V and high current of 2.02 nA. A book-shaped triboelectric energy harvester module (TEHM) was manufactured with polydimethylsiloxane on one side and the CB/BNT-ST nanofibers on the other side, affording an improved output performance with a high voltage of 391 V and high current of 130 μA. A book-shaped all-in-one hybrid energy harvester module (HEHM) was then manufactured by fitting PEHMs at both ends of the book-shaped TEHMs. As a result of optimizing the output performance by connecting HEHM multiple layers, a high voltage and current of 1043 V and 579 μA were observed, respectively, and charging of a 1.0 μF capacitor was completed in 25 s. Furthermore, in simulated energy harvesting experiments using the all-in-one HEHM, LED light bulbs were clearly illuminated in real time, and an electronic calculator was operated without charging. This work suggests the application potential of the all-in-one HEHM as the next generation of eco-friendly flexible energy sources.