Boron adsorption mechanism of a hybrid gel derived from tetraethoxysilane and bis(trimethoxysilylpropyl)amine

Haining Liu; Binju Qing; Xiushen Ye; Min Guo; Quan Li; Zhijian Wu; Kitae Lee; Deokkyu Lee; Kangtaek Lee

doi:10.1016/j.cap.2009.06.002

Boron adsorption mechanism of a hybrid gel derived from tetraethoxysilane and bis(trimethoxysilylpropyl)amine

Haining Liu, Binju Qing, Xiushen Ye, Min Guo, Quan Li, Zhijian Wu, Kitae Lee, Deokkyu Lee, Kangtaek Lee

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

An organic/inorganic hybrid gel was prepared with tetraethoxysilane (TEOS) and bis(trimethoxysilylpropyl)amine (TSPA) as precursors. The adsorption of boron on the hybrid gel in aqueous solutions was investigated comprehensively by varying the initial boron concentration, pH, ionic strength, and temperature. The equilibrium adsorption amount of boron increases with the increase in initial boron concentration and ionic strength, but decreases with the increase in temperature. The adsorption amount exhibits a maximum at initial pH of 4-10. Boron appears to be adsorbed in both H₃BO₃ and B(OH)₄^- forms through the hydrogen bonding, electrostatic and hydrophobic attractions.

Original language	English
Pages (from-to)	e280-e283
Journal	Current Applied Physics
Volume	9
Issue number	4 SUPPL.
DOIs	https://doi.org/10.1016/j.cap.2009.06.002
Publication status	Published - 2009 Jul

Bibliographical note

Funding Information:
ZW acknowledges the financial support by the foundation of Knowledge Innovation Program of Chinese Academy of Sciences (kzcx2-yw-115), and Hundred Talent Program of Chinese Academy of Sciences (0660011106). KL acknowledges the financial support by the KOSEF through the Grant No. M10755020001-08N5502-00110 and the National Core Research Center for Nanomedical Technology (R15-2004-024-00000-0).

All Science Journal Classification (ASJC) codes

Materials Science(all)
Physics and Astronomy(all)

Access to Document

10.1016/j.cap.2009.06.002

Cite this

@article{a95a5e4952654419806816354afc99fd,

title = "Boron adsorption mechanism of a hybrid gel derived from tetraethoxysilane and bis(trimethoxysilylpropyl)amine",

abstract = "An organic/inorganic hybrid gel was prepared with tetraethoxysilane (TEOS) and bis(trimethoxysilylpropyl)amine (TSPA) as precursors. The adsorption of boron on the hybrid gel in aqueous solutions was investigated comprehensively by varying the initial boron concentration, pH, ionic strength, and temperature. The equilibrium adsorption amount of boron increases with the increase in initial boron concentration and ionic strength, but decreases with the increase in temperature. The adsorption amount exhibits a maximum at initial pH of 4-10. Boron appears to be adsorbed in both H3BO3 and B(OH)4- forms through the hydrogen bonding, electrostatic and hydrophobic attractions.",

author = "Haining Liu and Binju Qing and Xiushen Ye and Min Guo and Quan Li and Zhijian Wu and Kitae Lee and Deokkyu Lee and Kangtaek Lee",

note = "Funding Information: ZW acknowledges the financial support by the foundation of Knowledge Innovation Program of Chinese Academy of Sciences (kzcx2-yw-115), and Hundred Talent Program of Chinese Academy of Sciences (0660011106). KL acknowledges the financial support by the KOSEF through the Grant No. M10755020001-08N5502-00110 and the National Core Research Center for Nanomedical Technology (R15-2004-024-00000-0).",

year = "2009",

month = jul,

doi = "10.1016/j.cap.2009.06.002",

language = "English",

volume = "9",

pages = "e280--e283",

journal = "Current Applied Physics",

issn = "1567-1739",

publisher = "Elsevier",

number = "4 SUPPL.",

}

TY - JOUR

T1 - Boron adsorption mechanism of a hybrid gel derived from tetraethoxysilane and bis(trimethoxysilylpropyl)amine

AU - Liu, Haining

AU - Qing, Binju

AU - Ye, Xiushen

AU - Guo, Min

AU - Li, Quan

AU - Wu, Zhijian

AU - Lee, Kitae

AU - Lee, Deokkyu

AU - Lee, Kangtaek

N1 - Funding Information: ZW acknowledges the financial support by the foundation of Knowledge Innovation Program of Chinese Academy of Sciences (kzcx2-yw-115), and Hundred Talent Program of Chinese Academy of Sciences (0660011106). KL acknowledges the financial support by the KOSEF through the Grant No. M10755020001-08N5502-00110 and the National Core Research Center for Nanomedical Technology (R15-2004-024-00000-0).

PY - 2009/7

Y1 - 2009/7

N2 - An organic/inorganic hybrid gel was prepared with tetraethoxysilane (TEOS) and bis(trimethoxysilylpropyl)amine (TSPA) as precursors. The adsorption of boron on the hybrid gel in aqueous solutions was investigated comprehensively by varying the initial boron concentration, pH, ionic strength, and temperature. The equilibrium adsorption amount of boron increases with the increase in initial boron concentration and ionic strength, but decreases with the increase in temperature. The adsorption amount exhibits a maximum at initial pH of 4-10. Boron appears to be adsorbed in both H3BO3 and B(OH)4- forms through the hydrogen bonding, electrostatic and hydrophobic attractions.

AB - An organic/inorganic hybrid gel was prepared with tetraethoxysilane (TEOS) and bis(trimethoxysilylpropyl)amine (TSPA) as precursors. The adsorption of boron on the hybrid gel in aqueous solutions was investigated comprehensively by varying the initial boron concentration, pH, ionic strength, and temperature. The equilibrium adsorption amount of boron increases with the increase in initial boron concentration and ionic strength, but decreases with the increase in temperature. The adsorption amount exhibits a maximum at initial pH of 4-10. Boron appears to be adsorbed in both H3BO3 and B(OH)4- forms through the hydrogen bonding, electrostatic and hydrophobic attractions.

UR - http://www.scopus.com/inward/record.url?scp=71849115155&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=71849115155&partnerID=8YFLogxK

U2 - 10.1016/j.cap.2009.06.002

DO - 10.1016/j.cap.2009.06.002

M3 - Article

AN - SCOPUS:71849115155

SN - 1567-1739

VL - 9

SP - e280-e283

JO - Current Applied Physics

JF - Current Applied Physics

IS - 4 SUPPL.

ER -

Boron adsorption mechanism of a hybrid gel derived from tetraethoxysilane and bis(trimethoxysilylpropyl)amine

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this