Breathing-Dependent Redox Activity in a Tetrathiafulvalene-Based Metal-Organic Framework

Manuel Souto, Jorge Romero, Joaquín Calbo, Iñigo J. Vitórica-Yrezábal, José L. Zafra, Juan Casado, Enrique Ortí, Aron Walsh, Guillermo Mínguez Espallargas

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18 Citations (Scopus)

Abstract

"Breathing" metal-organic frameworks (MOFs) that involve changes in their structural and physical properties upon an external stimulus are an interesting class of crystalline materials due to their range of potential applications including chemical sensors. The addition of redox activity opens up a new pathway for multifunctional "breathing" frameworks. Herein, we report the continuous breathing behavior of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, showing a reversible swelling (up to ca. 40% of the volume cell) upon solvent adsorption. Importantly, the planarity of the TTF linkers is influenced by the breathing behavior of the MOF, directly impacting on its electrochemical properties and thus opening the way for the development of new electrochemical sensors. Quantum chemical calculations and Raman spectroscopy have been used to provide insights into the tunability of the oxidation potential.

Original languageEnglish
Pages (from-to)10562-10569
Number of pages8
JournalJournal of the American Chemical Society
Volume140
Issue number33
DOIs
Publication statusPublished - 2018 Aug 22

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All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Souto, M., Romero, J., Calbo, J., Vitórica-Yrezábal, I. J., Zafra, J. L., Casado, J., Ortí, E., Walsh, A., & Mínguez Espallargas, G. (2018). Breathing-Dependent Redox Activity in a Tetrathiafulvalene-Based Metal-Organic Framework. Journal of the American Chemical Society, 140(33), 10562-10569. https://doi.org/10.1021/jacs.8b05890