Carbazole-containing porphyrinoid and its oligomers

Tongjing Wu, Taeyeon Kim, Bangshao Yin, Kaisheng Wang, Ling Xu, Mingbo Zhou, Dongho Kim, Jianxin Song

Research output: Contribution to journalArticle

Abstract

A novel carbazole-containing porphyrinoid 4H and its oligomers 6H and 7H were synthesized for the first time via the Suzuki-Miyaura cross-coupling reaction. The structures of 4H, 4Pd, 6H, and 6Zn were finally confirmed by X-ray analysis. The exciton coupling strength (628 cm-1) in 4Zn, 6Zn, and 7Zn was found to be larger than that of the directly-linked porphyrin arrays (570 cm-1), extending their absorption spectra to the NIR region as well as enhancing the extinction coefficients.

Original languageEnglish
Pages (from-to)11454-11457
Number of pages4
JournalChemical Communications
Volume55
Issue number76
DOIs
Publication statusPublished - 2019 Jan 1

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Porphyrins
X ray analysis
Oligomers
Excitons
Absorption spectra
LDS 751
carbazole

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Wu, T., Kim, T., Yin, B., Wang, K., Xu, L., Zhou, M., ... Song, J. (2019). Carbazole-containing porphyrinoid and its oligomers. Chemical Communications, 55(76), 11454-11457. https://doi.org/10.1039/c9cc06114b
Wu, Tongjing ; Kim, Taeyeon ; Yin, Bangshao ; Wang, Kaisheng ; Xu, Ling ; Zhou, Mingbo ; Kim, Dongho ; Song, Jianxin. / Carbazole-containing porphyrinoid and its oligomers. In: Chemical Communications. 2019 ; Vol. 55, No. 76. pp. 11454-11457.
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Wu, T, Kim, T, Yin, B, Wang, K, Xu, L, Zhou, M, Kim, D & Song, J 2019, 'Carbazole-containing porphyrinoid and its oligomers', Chemical Communications, vol. 55, no. 76, pp. 11454-11457. https://doi.org/10.1039/c9cc06114b

Carbazole-containing porphyrinoid and its oligomers. / Wu, Tongjing; Kim, Taeyeon; Yin, Bangshao; Wang, Kaisheng; Xu, Ling; Zhou, Mingbo; Kim, Dongho; Song, Jianxin.

In: Chemical Communications, Vol. 55, No. 76, 01.01.2019, p. 11454-11457.

Research output: Contribution to journalArticle

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AU - Zhou, Mingbo

AU - Kim, Dongho

AU - Song, Jianxin

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Wu T, Kim T, Yin B, Wang K, Xu L, Zhou M et al. Carbazole-containing porphyrinoid and its oligomers. Chemical Communications. 2019 Jan 1;55(76):11454-11457. https://doi.org/10.1039/c9cc06114b