Carbonation of Chrysotile under Subduction Conditions

Mihye Kong, Yongjae Lee

Research output: Contribution to journalArticle

Abstract

In order to understand the role of serpentine minerals in the global carbon cycle, high-pressure X-ray diffraction (XRD) experiments were performed on chrysotile (Mg3Si2O5(OH)4) using carbon dioxide (CO2) as a pressure medium. Synchrotron XRD patterns revealed the formation of magnesite and high-pressure chrysotile after heating at 170 °C for 1 h at 2.5(1) GPa. The Rietveld refinement suggests that the unit cell composition of the original chrysotile changes to Mg2.4(1)Si2O5(OH)2.4(1) upon the formation of magnesite, which appears to be driven by the dehydrogenation of the innermost hydroxyl group, OH3, and the rearrangement of magnesium (Mg) at the M1 site, leading to the formation of metastable monodehydroxylated chrysotile. Metastable chrysotile is observed up to 5.0(1) GPa and 500 °C, which corresponds to the slab Moho geotherms for the South Sumatra and Ryukyu subduction zone. After recovery to ambient conditions, the characteristic fibrous morphology of the original chrysotile was found to have changed to an earthy form. These results can help us to understand deep carbon cycling along the subduction zones, and may prompt the design of a novel method of asbestos detoxification using pressure and temperature.

Original languageEnglish
Pages (from-to)490-497
Number of pages8
JournalEngineering
Volume5
Issue number3
DOIs
Publication statusPublished - 2019 Jun 1

Fingerprint

Serpentine Asbestos
Carbonation
Magnesite
X ray diffraction
Detoxification
Rietveld refinement
Carbon
Asbestos
Dehydrogenation
Synchrotrons
Diffraction patterns
Magnesium
Carbon dioxide
Minerals
Heating
Recovery
Carbon Dioxide
Hydroxyl Radical
Chemical analysis
Experiments

All Science Journal Classification (ASJC) codes

  • Computer Science(all)
  • Environmental Engineering
  • Chemical Engineering(all)
  • Materials Science (miscellaneous)
  • Energy Engineering and Power Technology
  • Engineering(all)

Cite this

Kong, Mihye ; Lee, Yongjae. / Carbonation of Chrysotile under Subduction Conditions. In: Engineering. 2019 ; Vol. 5, No. 3. pp. 490-497.
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Carbonation of Chrysotile under Subduction Conditions. / Kong, Mihye; Lee, Yongjae.

In: Engineering, Vol. 5, No. 3, 01.06.2019, p. 490-497.

Research output: Contribution to journalArticle

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