Carborane-based metal-organic frameworks as highly selective sorbents for CO2 over methane

Youn-Sang Bae, Omar K. Farha, Alexander M. Spokoyny, Chad A. Mirkin, Joseph T. Hupp, Randall Q. Snurr

Research output: Contribution to journalArticle

283 Citations (Scopus)

Abstract

Separation of CO2/CH4 mixtures was studied in carborane-based metal-organic framework materials with and without coordinatively unsaturated metal sites; high selectivities for CO2 over CH4 (∼17) are obtained, especially in the material with open metal sites.

Original languageEnglish
Pages (from-to)4135-4137
Number of pages3
JournalChemical Communications
Issue number35
DOIs
Publication statusPublished - 2008 Sep 24

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Methane
Sorbents
Metals

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Bae, Y-S., Farha, O. K., Spokoyny, A. M., Mirkin, C. A., Hupp, J. T., & Snurr, R. Q. (2008). Carborane-based metal-organic frameworks as highly selective sorbents for CO2 over methane. Chemical Communications, (35), 4135-4137. https://doi.org/10.1039/b805785k
Bae, Youn-Sang ; Farha, Omar K. ; Spokoyny, Alexander M. ; Mirkin, Chad A. ; Hupp, Joseph T. ; Snurr, Randall Q. / Carborane-based metal-organic frameworks as highly selective sorbents for CO2 over methane. In: Chemical Communications. 2008 ; No. 35. pp. 4135-4137.
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Carborane-based metal-organic frameworks as highly selective sorbents for CO2 over methane. / Bae, Youn-Sang; Farha, Omar K.; Spokoyny, Alexander M.; Mirkin, Chad A.; Hupp, Joseph T.; Snurr, Randall Q.

In: Chemical Communications, No. 35, 24.09.2008, p. 4135-4137.

Research output: Contribution to journalArticle

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AU - Farha, Omar K.

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AU - Hupp, Joseph T.

AU - Snurr, Randall Q.

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