Catalyst coating of 3D printed structures via electrochemical deposition: Case of the transition metal chalcogenide MoSx for hydrogen evolution reaction

Christian Iffelsberger, Siowwoon Ng, Martin Pumera

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

Fused filament modeling (FFM) is the most common and simplest type of 3D printing. Conductive composite filaments have become widely used for 3D printing of electrodes and electrochemical devices for sensing, energy storage and energy conversion applications. To enhance the electrochemical performance of the 3D printed parts, post printing procedures are applied. These for example consist of atomic layer deposition, which is high-end equipment demanding. We offer simple, scalable and room temperature method of coating the 3D-printed electrode surfaces via desired catalyst via electrodeposition. We show the electrodeposition of MoSx which is highly catalytic to hydrogen evolution reaction as a case study of such thin film electrodeposition. The applicability of the self-standing 3D printed nanostructure for energy conversion purposes is demonstrated. Valuable information about the heterogeneity of the activity of the catalyst is provided by the scanning electrochemical microscopy (SECM). Electrodeposition is a universal technique which allows turning the surface of 3D objects into catalysts.

Original languageEnglish
Article number100654
JournalApplied Materials Today
Volume20
DOIs
Publication statusPublished - 2020 Sep

Bibliographical note

Funding Information:
M.P. acknowledges the financial support by the Grant Agency of the Czech Republic ( GACR EXPRO: 19-26896X ).

Funding Information:
CzechNanoLab project LM2018110 funded by MEYS CR is gratefully acknowledged for the financial support of the measurements/sample fabrication at CEITEC Nano Research Infrastructure (S.N.).

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

Fingerprint Dive into the research topics of 'Catalyst coating of 3D printed structures via electrochemical deposition: Case of the transition metal chalcogenide MoS<sub>x</sub> for hydrogen evolution reaction'. Together they form a unique fingerprint.

Cite this