Catalyst deactivation and regeneration in low temperature ethanol steam reforming with Rh/CeO2-ZrO2 catalysts

Hyun Seog Roh, Alexandru Platon, Yong Wang, David L. King

Research output: Contribution to journalArticlepeer-review

93 Citations (Scopus)

Abstract

Rh/CeO2-ZrO2 catalysts with various CeO 2/ZrO2 ratios have been applied to H2 production from ethanol steam reforming at low temperatures. The catalysts all deactivated with time on stream (TOS) at 350°C. The addition of 0.5% K has a beneficial effect on catalyst stability, while 5% K has a negative effect on catalytic activity. The catalyst could be regenerated considerably even at ambient temperature and could recover its initial activity after regeneration above 200°C with 1% O2. The results are most consistent with catalyst deactivation due to carbonaceous deposition on the catalyst.

Original languageEnglish
Pages (from-to)1-6
Number of pages6
JournalCatalysis Letters
Volume110
Issue number1-2
DOIs
Publication statusPublished - 2006 Aug

Bibliographical note

Funding Information:
This work was supported by Department of Energy’s Office of Hydrogen, Fuel Cells, and Infrastructure Technologies. Most of work was performed in the Environmental Molecular Science Laboratory, a national scientific user facility sponsored by the U.S. Department of Energy’s Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory in Richland, WA.

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Fingerprint Dive into the research topics of 'Catalyst deactivation and regeneration in low temperature ethanol steam reforming with Rh/CeO<sub>2</sub>-ZrO<sub>2</sub> catalysts'. Together they form a unique fingerprint.

Cite this